2-[2′-(phenylsulfonyl)ethyl]cyclopentanone

被引：0

作者：

Loughlin, WA ^{[1
]}

McCleary, MA ^{[1
]}

Healy, PC ^{[1
]}

机构：

[1] Griffith Univ, Sch Sci, Brisbane, Qld 4111, Australia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷

关键词：

D O I：

10.1107/S1600536802021335

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title compound, C13H16O3S, prepared by the reaction of the lithium enolate of cyclopentanone with phenylvinyl sulfoxide and subsequent oxidation with m-chloroperoxybenzoic acid (m-CPBA), shows the phenylsulfonylethyl side chain to be bonded to the cyclopentanone ring in a pseudo-equatorial orientation.

引用

页码：O1418 / O1420

页数：3

共 13 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
ALLEN, FH
KENNARD, O
WATSON, DG
BRAMMER, L
ORPEN, AG
TAYLOR, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
[2] New efficient and stereoselective [2+2] cycloadditions of dimethylaluminum enolates with phenylvinylsulfoxide
Bienayme, H
Guicher, N
[J]. TETRAHEDRON LETTERS, 1997, 38 (31) : 5511 - 5514
[3] ALKENYL SULFOXIDES AS PRECURSORS TO CYCLOPENTENONES AND PROSTANOID BETA-SIDE CHAINS
BROWN, PJ
JONES, DN
KHAN, MA
MEANWELL, NA
[J]. TETRAHEDRON LETTERS, 1983, 24 (04) : 405 - 408
[4] ELIEL EL, 1965, CONFORMATIONAL ANALY, P113
[5] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI)
[J]. Journal of Applied Crystallography, 1997, 30 (pt 5)
[6] Investigations into the reaction of the lithium enolate of cyclohexanone and phenyl vinyl sulfoxide: A simple synthesis of a bicyclo[4.2.0]octan-1-ol
Loughlin, WA
Rowen, CC
Healy, PC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2002, (02): : 296 - 302
[7] *MOL STRUCT CORP, 1999, MSC AFC 7 DIFFR CONT
[8] *MOL STRUCT CORP, 1997, TEXSAN WIND VERS 1 0
[9] INTRODUCTION OF THE 2-(PHENYLTHIO)ETHYL, 2-(PHENYLSULFINYL)ETHYL, AND 2,2-BIS(PHENYLTHIO)ETHYL SUBSTITUENTS INTO CYCLIC-KETONES
MONTGOMERY, J
OVERMAN, LE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (23) : 6476 - 6479
[10] REGIOSELECTIVE MONOALKYLATION OF KETONES WITH ALLYLIC NITRO-COMPOUNDS
ONO, N
HAMAMOTO, I
KAJI, A
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (06) : 1863 - 1864

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