Practical Synthesis of B(9)-Halogenated Carboranes with N-Haloamides in Hexafluoroisopropanol

被引：24
作者：
Guo, Wenjing [1 ,2 ]
Guo, Chenyang [3 ]
Ma, Yan-Na [1 ,2 ]
Chen, Xuenian [1 ,2 ]
机构：
[1] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Henan, Peoples R China
[2] Zhengzhou Univ, Inst Green Catalysis, Zhengzhou 450001, Henan, Peoples R China
[3] Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 13期
基金：
中国国家自然科学基金;
关键词：
O-CARBORANES; B-N; FACILE SYNTHESIS; BORON; DERIVATIVES; BONDS; SUBSTITUTION; ARYLATION; SERIES; 1,2-DICARBACLOVODODECABORANE(12);
D O I：
10.1021/acs.inorgchem.2c00074
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The B(9)-H halogenation of o-carborane and m-carborane was achieved with excellent selectivities in hexafluor-oisopropanol (HFIP) under simple reaction conditions: singlereagent [trichloroisocyanuric acid (TCCA), tribromoisocyanuricacid (TBCA) orN-iodosuccinimide (NIS)], catalyst-free, air-/moisture-tolerant, and convenient work-up. With this method, avariety of 9-halogenatedo-carboranes andm-carboranes were obtained in good to excellent yields with broad tolerance of functional groups
引用
收藏
页码：5326 / 5334
页数：9
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