Synthesis and Conformational Analysis of Phosphine Selenides

被引：4

作者：

Malysheva, S. F. ^{[1
]}

Belogorlova, N. A. ^{[1
]}

Vereshchagina, Ya. A. ^{[2
]}

Alimova, A. Z. ^{[2
]}

Ishmaeva, E. A. ^{[2
]}

Chachkov, D. V. ^{[3
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Favorskii Irkutsk Inst Chem, Irkutsk 664003, Russia

[2] Kazan Fed Univ, Ul Kremlevskaya 18, Kazan 420008, Tatarstan, Russia

[3] Russian Acad Sci, Joint Supercomp Ctr, Kazan Branch, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

phosphine selenide; the Trofimov-Gusarova reaction; polarity; conformational analysis; quantum chemical calculation; ATOM-ECONOMIC SYNTHESIS; RED PHOSPHORUS; ELEMENTAL PHOSPHORUS; NUCLEOPHILIC-ADDITION; VIBRATIONAL-SPECTRA; DIPOLE-MOMENTS; KOH-DMSO; CHALCOGENIDES; TRIS(2-PYRIDYL)PHOSPHINE; 2-BROMOPYRIDINE;

D O I：

10.1134/S1070363216030154

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methods of preparation of complex phosphine selenide via the original Trofimov-Gusarova reaction are described. The results of the products conformational analysis by means of a set of physical methods (IR spectroscopy, dipole moments, and quantum chemical calculation) are presented.

引用

页码：590 / 601

页数：12

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