Direct Coupling of Naphthalene and Sulfonimides Promoted by DDQ and Blue Light

被引：20

作者：

Sakakibara, Yota ^{[1
,2
]}

Ito, Eri ^{[1
,2
]}

Kawakami, Takahiro ^{[1
,2
]}

Yamada, Shuya ^{[1
,2
]}

Murakami, Kei ^{[1
,2
]}

Itami, Kenichiro ^{[1
,2
,3
]}

机构：

[1] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[3] Nagoya Univ, Itami Mol Nanocarbon Project, JST ERATO, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

CHEMISTRY LETTERS | 2017年 / 46卷 / 07期

关键词：

Aromatic C-H amination; DDQ; Blue light; C-H AMINATION; IMIDATION; ARENES; AMIDATION; HETEROARENES; CATALYSIS; MILD;

D O I：

10.1246/cl.170321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aromatic C-H amination chemistry has attracted significant attention as an alternative to conventional amination of aryl halides. Among C-H amination reactions, dehydrogenative coupling of arenes and N-H reagents represents an ideal transformation because prefunctionalization steps of arenes or aminating reagents are not required. Herein, we report direct C-H/N-H coupling between naphthalene and sulfonimides mediated by 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) as a photosensitizer under irradiation of blue light.

引用

收藏

页码：1014 / 1016

页数：3

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