Silver N-heterocyclic carbenes: emerging powerful catalysts

被引：37

作者：

Wang, Zikun ^{[1
]}

Tzouras, Nikolaos V. ^{[2
]}

Nolan, Steven P. ^{[2
]}

Bi, Xihe ^{[1
]}

机构：

[1] Northeast Normal Univ, Dept Chem, Changchun 130024, Peoples R China

[2] Univ Ghent, Dept Chem, Krijgslaan 281 S-3, B-9000 Ghent, Belgium

来源：

TRENDS IN CHEMISTRY | 2021年 / 3卷 / 08期

基金：

中国国家自然科学基金; 比利时弗兰德研究基金会;

关键词：

QUATERNARY STEREOGENIC CENTERS; RING-OPENING POLYMERIZATION; ALLYLIC ALKYLATION; TERMINAL ALKYNES; CARBON-DIOXIDE; ENANTIOSELECTIVE SYNTHESIS; CONJUGATE ADDITIONS; EFFICIENT CATALYSTS; SILVER(I)-CARBENE COMPLEXES; AG(I) COMPLEXES;

D O I：

10.1016/j.trechm.2021.04.006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Silver N-heterocyclic carbenes (Ag-NHCs) exhibit good biocompatibility and have found a wide range of applications in medicine and coordination chemistry. However, due to the strong sigma donor nature of NHC, its coordination with silver can weaken the Lewis acidity of Ag(I), leading to slow development of Ag-NHCs in the field of catalysis. Here, we systematically review the application of Ag-NHCs as catalysts in organic synthesis and clearly elaborate the reasons for the slow development of Ag-NHCs in the field of catalysis along with future development opportunities for such complexes as catalysts.

引用

页码：674 / 685

页数：12

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