Green synthesis of ZnO nanoparticles using Carica papaya leaf extracts for photocatalytic and photovoltaic applications

被引:126
作者
Rathnasamy, Rajeswari [1 ,2 ]
Thangasamy, Pitchai [2 ]
Thangamuthu, Rangasamy [3 ]
Sampath, Sridhar [1 ]
Alagan, Viswanathan [1 ]
机构
[1] Anna Univ, Dept Phys, Bharathidasan Inst Technol BIT Campus, Tiruchirappalli 620024, Tamil Nadu, India
[2] Cent Electrochem Res Inst, Council Sci & Ind Res, Funct Mat Div, Karaikkudi 630003, Tamil Nadu, India
[3] Cent Electrochem Res Inst, Council Sci & Ind Res, Electrochem Mat Sci, Karaikkudi 630003, Tamil Nadu, India
关键词
ZINC-OXIDE NANOPARTICLES; SENSITIZED SOLAR-CELLS; DEGRADATION; NANOSTRUCTURES; OPTIMIZATION; PERFORMANCE; OXIDATION; QUANTUM;
D O I
10.1007/s10854-017-6807-8
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We report a facile synthesis of hexagonal wurtzite ZnO nanoparticles through green synthesis method using Carica papaya leaf extract. To understand the structural phase purity, morphology and size, the sample was characterized through various analytical techniques. The obtained results reveal that the synthesized ZnO nanoparticle is a phase pure hexagonal wurtzite structure in spherical shape with particle size of similar to 50 nm. Furthermore, the synthesized ZnO nanoparticles were used as photocatalyst as well as photo anode for methylene blue dye degradation and dye sensitized solar cells, respectively. It was found that the synthesized ZnO nanoparticles completely degrade the methylene blue dye within 180 min under UV light irradiation. In addition, it shows an energy conversion efficiency of 1.6% with a current density of 8.1 mA cm(-2) in dye sensitized solar cells.
引用
收藏
页码:10374 / 10381
页数:8
相关论文
共 38 条
[1]   Principles and mechanisms of photocatalytic dye degradation on TiO2 based photocatalysts: a comparative overview [J].
Ajmal, Anila ;
Majeed, Imran ;
Malik, Riffat Naseem ;
Idriss, Hicham ;
Nadeem, Muhammad Amtiaz .
RSC ADVANCES, 2014, 4 (70) :37003-37026
[2]   Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: A review [J].
Akpan, U. G. ;
Hameed, B. H. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 170 (2-3) :520-529
[3]   Phytosynthesis of silver nanoparticles using Coccinia grandis leaf extract and its application in the photocatalytic degradation [J].
Arunachalam, Rajeswari ;
Dhanasingh, Sujatha ;
Kalimuthu, Balasaraswathi ;
Uthirappan, Mani ;
Rose, Chellan ;
Mandal, Asit Baran .
COLLOIDS AND SURFACES B-BIOINTERFACES, 2012, 94 :226-230
[4]  
Awwad A.M., 2014, ADV MAT LETT, V5, P520, DOI DOI 10.5185/AMLETT.2014.5575
[5]   Room-temperature synthesis of zinc oxide nanoparticles in different media and their application in cyanide photodegradation [J].
Bagabas, Abdulaziz ;
Alshammari, Ahmad ;
Aboud, Mohamed F. A. ;
Kosslick, Hendrik .
NANOSCALE RESEARCH LETTERS, 2013, 8 :1-10
[6]   PHOTOCATALYTIC OXIDATION OF ORGANIC-ACIDS ON QUANTUM-SIZED SEMICONDUCTOR COLLOIDS [J].
CARRAWAY, ER ;
HOFFMAN, AJ ;
HOFFMANN, MR .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (05) :786-793
[7]   Recent developments of metal oxide semiconductors as photocatalysts in advanced oxidation processes (AOPs) for treatment of dye waste-water [J].
Chan, Samuel Hong Shen ;
Wu, Ta Yeong ;
Juan, Joon Ching ;
Teh, Chee Yang .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2011, 86 (09) :1130-1158
[8]   Efficient electron transport in ZnO nanowire/nanoparticle dye-sensitized solar cells via continuous flow injection process [J].
Chen, Liang-Yih ;
Yin, Yu-Tung .
RSC ADVANCES, 2013, 3 (22) :8480-8488
[9]   A novel tetragonal pyramid-shaped porous ZnO nanostructure and its application in the biosensing of horseradish peroxidase [J].
Dai, Zhihui ;
Liu, Ke ;
Tang, Yawen ;
Yang, Xiaodi ;
Bao, Jianchun ;
Shen, Jian .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (16) :1919-1926
[10]   Correlation between photoluminescence spectra with gas sensing and photocatalytic activities in hierarchical ZnO nanostructures [J].
Do, T. Anh Thu ;
Ho Truong Giang ;
Do Van Huong ;
Pham Quang Ngan ;
Giang Hong Thai ;
Do Thi Thu ;
Tran Dai Lam .
RSC ADVANCES, 2017, 7 (16) :9826-9832