Ligand-centered reactivity of organometallic radicals

被引：64
作者：
Torraca, KE [1 ]
McElwee-White, L [1 ]
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷
基金：
美国国家科学基金会;
关键词：
organometallic radicals; free radical addition; ligand-ligand coupling;
D O I：
10.1016/S0010-8545(99)00253-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Due to the increasing number of odd-electron organometallic species implicated in catalytic processes, interest in such compounds has risen. Although the prior emphasis in the literature was on metal-centered reactivity, reports of radical reactivity within ligands have recently become more common and a wider variety of reactions have been observed. This review serves as an overview of ligand-centered reactions of organometallic radicals with emphasis on the recent literature. (C) 2000 Elsevier Science S.A. All rights reserved.
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收藏
页码：469 / 491
页数：23
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