Electric field induced cubic to monoclinic phase transition in multiferroic 0.65Bi(Ni1/2Ti1/2)O3-0.35PbTiO3 solid solution
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Pandey, Rishikesh
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Banaras Hindu Univ, Sch Mat Sci & Technol, Indian Inst Technol, Varanasi 221005, Uttar Pradesh, IndiaBanaras Hindu Univ, Sch Mat Sci & Technol, Indian Inst Technol, Varanasi 221005, Uttar Pradesh, India
Pandey, Rishikesh
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Singh, Akhilesh Kumar
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[1] Banaras Hindu Univ, Sch Mat Sci & Technol, Indian Inst Technol, Varanasi 221005, Uttar Pradesh, India
The results of x-ray diffraction studies on 0.65Bi(Ni1/2Ti1/2)O-3-0.35PbTiO(3) solid solution poled at various electric fields are presented. After poling, significant value of planar electromechanical coupling coefficient (k(P)) is observed for this composition having cubic structure in unpoled state. The cubic structure of 0.65Bi(Ni1/2Ti1/2)O-3-0.35PbTiO(3) transforms to monoclinic structure with space group Pm for the poling field >= 5 kV/cm. Large c-axis microscopic lattice strain (1.6%) is achieved at 30 kV/cm poling field. The variation of the c-axis strain and unit cell volume with poling field shows a drastic jump similar to that observed for strain versus electric field curve in (1 = x)Pb(Mg1/3Nb2/3)O-3-xPbTiO(3) and (1 = x)Pb(Zn1/3Nb2/3)O-3-xPbTiO(3). (C) 2014 AIP Publishing LLC.
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CNR ISC, Ist Sistemi Complessi, Area Ric Roma Tor Vergata, I-00133 Rome, ItalyCNR ISC, Ist Sistemi Complessi, Area Ric Roma Tor Vergata, I-00133 Rome, Italy
Craciun, F.
Galassi, C.
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CNR ISTEC, Ist Sci & Tecnol Mat Ceram, I-48018 Faenza, ItalyCNR ISC, Ist Sistemi Complessi, Area Ric Roma Tor Vergata, I-00133 Rome, Italy
Galassi, C.
Birjega, R.
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NILPRP, RO-77125 Bucharest, RomaniaCNR ISC, Ist Sistemi Complessi, Area Ric Roma Tor Vergata, I-00133 Rome, Italy
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CNR ISC, Ist Sistemi Complessi, Area Ric Roma Tor Vergata, I-00133 Rome, ItalyCNR ISC, Ist Sistemi Complessi, Area Ric Roma Tor Vergata, I-00133 Rome, Italy
Craciun, F.
Galassi, C.
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CNR ISTEC, Ist Sci & Tecnol Mat Ceram, I-48018 Faenza, ItalyCNR ISC, Ist Sistemi Complessi, Area Ric Roma Tor Vergata, I-00133 Rome, Italy
Galassi, C.
Birjega, R.
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NILPRP, RO-77125 Bucharest, RomaniaCNR ISC, Ist Sistemi Complessi, Area Ric Roma Tor Vergata, I-00133 Rome, Italy