Supramolecular liquid crystals induced by intermolecular hydrogen bonding between benzoic acid and 4-(alkoxyphenylazo) pyridines

被引:33
作者
Song, XZ [1 ]
Li, JX [1 ]
Zhang, SW [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
关键词
D O I
10.1080/0267829031000071284
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supramolecular liquid crystalline complexes have been obtained from binary mixtures of 4-(alkoxyphenylazo)pyridines and 4-octyloxylbenzoic acid. None of the pyridine-based derivatives is mesomorphic, but the hydrogen-bonded complexes are. Their liquid crystalline properties were investigated by DSC, polarizing optical microscopy, FTIR spectroscopy and powder X-ray diffraction. The complexes exhibit enantiotropic smectic C phases.
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页码:331 / 335
页数:5
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