Synthesis and characterization of aryl boron-containing thermoplastic phenolic resin with high thermal decomposition temperature and char yield

被引：20

作者：

Feng, Junjun ^{[1
]}

Chen, Lixin ^{[1
]}

Gu, Junwei ^{[1
]}

He, Zeyu ^{[1
]}

Yun, Jin ^{[1
]}

Wang, Xiaobin ^{[1
]}

机构：

[1] Northwestern Polytech Univ, Dept Appl Chem, Sch Sci, Key Lab Space Appl Phys & Chem,Minist Educ, Xian 710072, Shaanxi, Peoples R China

来源：

JOURNAL OF POLYMER RESEARCH | 2016年 / 23卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Aryl boron-containing thermoplastic phenolic resin; Softening points; Thermal stabilities; Char yield ratio; MECHANICAL-PROPERTIES; STABILITY; NANOCOMPOSITES; COMPOSITES; RESISTANCE; MORPHOLOGY; PYROLYSIS; GRAPHITE;

D O I：

10.1007/s10965-016-0966-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Phenol, zinc acetate dihydrate and paraformaldehyde are firstly performed to synthesize thermoplastic phenolic resin (PR), then phenylboronic acid (PBA) and other two boron compounds (4-hydroxymethyl phenylboronic acid & boronic acid) are introduced to fabricate the boron-containing thermoplastic phenolic resins (BPRs). The corresponding molecular structure, softening points, thermal decomposition temperature and char yield ratio of the BPRs are characterized and investigated by FTIR, NMR, XPS and TGA. Compared to pure thermoplastic PR, all the BPRs present relatively higher softening points, more excellent thermal decomposition temperature and higher char yield values. BPR-a exhibits the optimal thermal decomposition temperature (T (5) of 317.4 A degrees C) and char yield ratio at 800 A degrees C (69.6 %).

引用

页码：1 / 7

页数：7

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