CO•••H2O bonding in and on porous ices

被引:9
作者
Givan, A
Loewenschuss, A [1 ]
Nielsen, CJ
机构
[1] Hebrew Univ Jerusalem, Dept Inorgan & Analyt Chem, IL-91904 Jerusalem, Israel
[2] Univ Oslo, Dept Chem, N-0315 Oslo, Norway
关键词
infrared spectrometry; water ices; CO*H2O complexes; CO adsorption;
D O I
10.1016/S0924-2031(97)00044-1
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Spectra of H2O in solid CO are presented and compared to results obtained for CO adsorbed on different water ices. By the shape of the nu(OH) features, CO association to well separated dangling OH bonds and to water polymeric structures may be distinguished. It is suggested that the CO clusters, formed by CO depositon onto ices of bulk porosity, surround narrow, hair like protrusions of the ice voids. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:85 / 88
页数:4
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