Layered Metal Hydroxides and Their Derivatives: Controllable Synthesis, Chemical Exfoliation, and Electrocatalytic Applications

被引:137
作者
Chen, Gen [1 ]
Wan, Hao [1 ]
Ma, Wei [2 ]
Zhang, Ning [1 ]
Cao, Yijun [2 ]
Liu, Xiaohe [1 ]
Wang, Jun [1 ]
Ma, Renzhi [3 ]
机构
[1] Cent South Univ, Sch Minerals Proc & Bioengn, Sch Mat Sci & Engn, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
[2] Zhengzhou Univ, Sch Chem Engn & Energy, Res Ctr Heterogeneous Catalysis & Engn Sci, Zhengzhou 450001, Henan, Peoples R China
[3] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton WPI MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
基金
中国国家自然科学基金;
关键词
controllable synthesis; derivative; electrocatalysis; exfoliation; layered metal hydroxide; HYDROGEN EVOLUTION REACTION; OXYGEN REDUCTION REACTION; ELECTROCHEMICAL ENERGY-STORAGE; ONE-STEP SYNTHESIS; COBALT HYDROXIDE; BIFUNCTIONAL ELECTROCATALYSTS; NICKEL-HYDROXIDE; WATER OXIDATION; RECENT PROGRESS; STRUCTURAL MODIFICATION;
D O I
10.1002/aenm.201902535
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Layered metal hydroxides (LMHs) are regarded as a novel and important class of inorganic functional materials. They have unique layered structure and variable chemical compositions that can be readily tuned. In this review, summarized are the recent advances of synthetic routes to the LMHs with designed morphology, composition, and function for electrocatalysis. Versatile products can be readily derived by hybridization, anion-exchange, surface modification, self-assembly, etc. More importantly, LMHs can be artificially exfoliated into unilamellar nanosheets with a molecular-level thickness of about 1 nm versus 2D lateral size in submicrometer or micrometer scale. Molecular-scale assembly can be then applied to fabricate superlattice-like composites and functional nanofilms with high quality. The hydroxides can be transformed into oxides, nitrides, or other compounds via different preparation procedures, which can further extend their application prospects. In this regard, the most promising electrocatalysis-related applications of LMHs and their derivatives are reviewed, such as oxygen evolution reaction, oxygen reduction reaction, hydrogen evolution reaction, CO2 reduction reaction, alcohol or urea electrooxidation, etc. At last, future challenges are also discussed from the aspect of synthesis and application, as well as encouraging advancements are anticipated.
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页数:27
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共 257 条
[1]   Hexagonal nanosheets from the exfoliation of Ni2+-Fe3+ LDHs: a route towards layered multifunctional materials [J].
Abellan, Gonzalo ;
Coronado, Eugenio ;
Marti-Gastaldo, Carlos ;
Pinilla-Cienfuegos, Elena ;
Ribera, Antonio .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (35) :7451-7455
[2]   Evolution of layered double hydroxides (LDH) as high performance water oxidation electrocatalysts: A review with insights on structure, activity and mechanism [J].
Anantharaj, Sengeni ;
Karthick, Kannimuthu ;
Kundu, Subrata .
MATERIALS TODAY ENERGY, 2017, 6 :1-26
[3]   2D metal carbides and nitrides (MXenes) for energy storage [J].
Anasori, Babak ;
Lukatskaya, Maria R. ;
Gogotsi, Yury .
NATURE REVIEWS MATERIALS, 2017, 2 (02)
[4]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[5]   The future of energy supply: Challenges and opportunities [J].
Armaroli, Nicola ;
Balzani, Vincenzo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (1-2) :52-66
[6]   Bifunctional 2D Electrocatalysts of Transition Metal Hydroxide Nanosheet Arrays for Water Splitting and Urea Electrolysis [J].
Babar, Pravin ;
Lokhande, Abhishek ;
Karade, Vijay ;
Pawar, Bharati ;
Gang, Myeng Gil ;
Pawar, Sambhaji ;
Kim, Jin Hyeok .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (11) :10035-10043
[7]   Cobalt Iron Hydroxide as a Precious Metal-Free Bifunctional Electrocatalyst for Efficient Overall Water Splitting [J].
Babar, Pravin ;
Lokhande, Abhishek ;
Shin, Hyeong Ho ;
Pawar, Bharati ;
Gang, Myeng Gil ;
Pawar, Sambhaji ;
Kim, Jin Hyeok .
SMALL, 2018, 14 (07)
[8]   Electrochemical Reduction of N2 under Ambient Conditions for Artificial N2 Fixation and Renewable Energy Storage Using N2/NH3 Cycle [J].
Bao, Di ;
Zhang, Qi ;
Meng, Fan-Lu ;
Zhong, Hai-Xia ;
Shi, Miao-Miao ;
Zhang, Yu ;
Yan, Jun-Min ;
Jiang, Qing ;
Zhang, Xin-Bo .
ADVANCED MATERIALS, 2017, 29 (03)
[9]   A ternary cobalt-molybdenum-vanadium layered double hydroxide nanosheet array as an efficient bifunctional electrocatalyst for overall water splitting [J].
Bao, Jian ;
Wang, Zhaolong ;
Xie, Junfeng ;
Xu, Li ;
Lei, Fengcai ;
Guan, Meili ;
Zhao, Yan ;
Huang, Yunpeng ;
Li, Huaming .
CHEMICAL COMMUNICATIONS, 2019, 55 (24) :3521-3524
[10]   Low concentration CO2 capture using physical adsorbents: Are metal-organic frameworks becoming the new benchmark materials? [J].
Belmabkhout, Youssef ;
Guillerm, Vincent ;
Eddaoudi, Mohamed .
CHEMICAL ENGINEERING JOURNAL, 2016, 296 :386-397