Engineering Permanent Porosity into Liquids

被引:76
作者
Jie, Kecheng [1 ]
Zhou, Yujuan [1 ,2 ]
Ryan, Hugh P. [1 ]
Dai, Sheng [3 ,4 ]
Nitschke, Jonathan R. [1 ]
机构
[1] Univ Cambridge, Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England
[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[3] Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37831 USA
[4] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
基金
欧洲研究理事会; 中国博士后科学基金; 英国工程与自然科学研究理事会;
关键词
adsorption; ionic liquids; microporosity; porous liquids; separation; TEMPERATURE IONIC LIQUIDS; CARBON-DIOXIDE CAPTURE; POROUS ORGANIC CAGES; FRAMEWORKS; SOLVENTS; PLATFORM;
D O I
10.1002/adma.202005745
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The possibility of engineering well-defined pores into liquid materials is fascinating from both a conceptual and an applications point of view. Although the concept of porous liquids was proposed in 2007, these materials had remained hypothetical due to the technical challenges associated with their synthesis. Over the past five years, however, reports of the successful construction of porous liquids based on existing porous scaffolds, such as coordination cages, organic cages, metal-organic frameworks, porous carbons, zeolites, and porous polymers, have started to emerge. Here, the focus is on these early reports of porous liquids as prototypes in the field, classified according to the previously defined types of porous liquids. Particular attention will be paid to design strategies and structure-property relationships. Porous liquids have already exhibited promising applications in gas storage, transportation, and chemical separations. Thus, they show great potential for use in the chemical industry. The challenges of preparation, scale-up, volatility, thermal and chemical stability, and competition with porous solids will also be discussed.
引用
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页数:18
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