Effect of Molybdenum Content on Mechanical and Tribological Properties of Diamond-Like Carbon Coatings over Titanium β-21S Alloy

被引：13
作者：
Padmanaban, Dilli Babu [1 ,2 ]
Mohan, Loganathan [1 ,3 ]
Giri, Preetam [1 ]
Bera, Parthasarathi [1 ]
Anandan, Chinnasamy [1 ]
Barshilia, Harish C. [1 ]
机构：
[1] Natl Aerosp Labs, CSIR, Surface Engn Div, Bengaluru 560017, India
[2] Ulster Univ Jordanstown, Sch Engn, Belfast BT37 0QB, Antrim, North Ireland
[3] Toyohashi Univ Technol, Dept Mech Engn, Toyohashi, Aichi 4418580, Japan
来源：
C-JOURNAL OF CARBON RESEARCH | 2021年 / 7卷 / 01期
关键词：
diamond-like carbon; molybdenum doping; titanium beta-21S; XPS; Raman spectroscopy; wear; COMPOSITE THIN-FILMS; CORROSION BEHAVIOR; DOPED DLC; SURFACE MODIFICATION; THERMAL-STABILITY; ION-IMPLANTATION; WEAR-RESISTANCE; RAMAN-SPECTRA; CATHODIC ARC; DEPOSITION;
D O I：
10.3390/c7010001
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Molybdenum-doped diamond-like carbon (Mo-DLC) coatings have been deposited on titanium beta-21S alloy (Ti-15Mo-3Nb-3Al-0.2Si) using plasma-enhanced chemical vapor deposition (PECVD) equipped with pulsed-DC magnetron sputtering. Mo contents in the deposited coatings have been controlled with an applied sputtering pulse duty cycle. Chemical composition, structure, morphology, and topography have been studied using X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and atomic force microscopy (AFM), respectively. XRD pattern of the coating with highest Mo content shows the presence of carbide phase. Smooth features with low roughness values are observed in low Mo content coating, whereas high Mo content coating shows granular characteristics with a high roughness value. Raman spectra reveal the increased graphitic content for the highest metal concentration in the coatings, wherein the nanohardness is also determined to be highest, at about similar to 18-19 GPa. Furthermore, the ball-on-disk tribometry test on Mo-DLC coating with highest nanohardness shows a low coefficient of friction (COF) of 0.2 with low wear loss compared to that of the substrate (0.62).
引用
收藏
页数：20
相关论文
共 90 条
[51]   Corrosion behavior of titanium alloy Beta-21S coated with diamond like carbon in Hank's solution [J].
Mohan, L. ;
Anandan, C. ;
Grips, V. K. William .
APPLIED SURFACE SCIENCE, 2012, 258 (17) :6331-6340
[52]   Electrophoretic deposition of nanocomposite (HAp + TiO2) on titanium alloy for biomedical applications [J].
Mohan, L. ;
Durgalakshmi, D. ;
Geetha, M. ;
Narayanan, T. S. N. Sankara ;
Asokamani, R. .
CERAMICS INTERNATIONAL, 2012, 38 (04) :3435-3443
[53]   Tribological response and characterization of Mo-W doped DLC coating [J].
Muller, Itzel Castillo ;
Sharp, Joanne ;
Rainforth, W. Mark ;
Hovsepian, Papken ;
Ehiasarian, Arutiun .
WEAR, 2017, 376 :1622-1629
[54]   Corrosion wear fracture of new β type biomedical titanium alloys [J].
Niinomi, M ;
Kuroda, D ;
Fukunaga, K ;
Morinaga, M ;
Kato, Y ;
Yashiro, T ;
Suzuki, A .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1999, 263 (02) :193-199
[55]   Development of Ti-Mo alloys for biomedical applications: Microstructure and electrochemical characterization [J].
Oliveira, Nilson T. C. ;
Aleixo, Giorgia ;
Caram, Rubens ;
Guastaldi, Antonio C. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 452 :727-731
[56]   Measurement of hardness and elastic modulus by instrumented indentation: Advances in understanding and refinements to methodology [J].
Oliver, WC ;
Pharr, GM .
JOURNAL OF MATERIALS RESEARCH, 2004, 19 (01) :3-20
[57]   Tuning the tribological property of PLD deposited DLC-Au nanocomposite thin films [J].
Panda, M. ;
Krishnan, R. ;
Krishna, N. G. ;
Amirthapandian, S. ;
Magudapathy, P. ;
Kamruddin, M. .
CERAMICS INTERNATIONAL, 2019, 45 (07) :8847-8855
[58]   Low-friction behaviour of boundary-lubricated diamond-like carbon coating's containing tungsten [J].
Podgornik, B ;
Hren, D ;
Vizintin, J .
THIN SOLID FILMS, 2005, 476 (01) :92-100
[59]   Mechanical Properties of DLC/Ti-O Bilayer Films [J].
Qi, F. ;
Leng, Y. X. ;
Sun, H. ;
Huang, N. .
IEEE TRANSACTIONS ON PLASMA SCIENCE, 2009, 37 (07) :1136-1139
[60]   Effect of the hydrogen on the intrinsic stress in hydrogenated amorphous carbon films deposited from an electron cyclotron resonance plasma [J].
Racine, B ;
Benlahsen, M ;
Zellama, K ;
Goudeau, P ;
Zarrabian, M ;
Turban, G .
APPLIED PHYSICS LETTERS, 1998, 73 (22) :3226-3228
123456789