Magnetization of Ultraviolet-Reduced Graphene Oxide Flakes in Composites Based on Polystyrene

被引:7
|
作者
Ionov, Alexander N. [1 ]
Volkov, Mikhail P. [1 ]
Nikolaeva, Marianna N. [2 ]
Smyslov, Ruslan Y. [2 ,3 ]
Bugrov, Alexander N. [2 ,4 ]
机构
[1] Ioffe Inst, Politekhn Skaya 26, St Petersburg 194021, Russia
[2] Russian Acad Sci, Inst Macromol Cpds, Bolshoy Pr T 31, St Petersburg 199004, Russia
[3] Peter Great St Petersburg Polytech Univ SPbPU, Grad Sch Biomed Syst & Technol, Inst Biomed Syst & Biotechnol, Polytechn Skaya 29, St Petersburg 195251, Russia
[4] St Petersburg Electrotech Univ ETU LETI, Dept Phys Chem, Ul Prof Popova 5, St Petersburg 197376, Russia
基金
俄罗斯基础研究基金会;
关键词
graphene-based materials; ultraviolet-holed graphene nanosheets; polymer-twisted graphene layers; magnetic properties; superconductivity; DEFECT-INDUCED MAGNETISM; THERMAL REDUCTION; GRAPHITE; PHOTOREDUCTION; PARAMAGNETISM; MATRIX;
D O I
10.3390/ma14102519
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work presents our study results of the magnetization of multilayer UV-reduced graphene oxide (UV-rGO), polymer matrix (polystyrene), and a conjugated composite based on them. The mesoscopic structure of the composites synthesized in this work was studied by such methods as X-ray diffraction, SEM, as well as NMR-, IR- and Raman spectroscopy. The magnetization of the composites under investigation and their components was measured using a vibrating-sample magnetometer. It has been shown that the UV-reduction process leads to the formation of many submicron holes distributed inside rGO flakes, which can create edge defects, causing possibly magnetic order in the graphite samples under investigation on the mesoscopic level. This article provides an alternative explanation for the ferromagnetic hysteresis loop in UV-rGO on the base of superconductivity type-II.
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页数:13
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