Electric field mediated on transport through charged mesoporous membranes

被引:0
|
作者
Schmuhl, R [1 ]
de Lint, WBS [1 ]
Keizer, K [1 ]
van den Berg, A [1 ]
ten Elshof, JE [1 ]
机构
[1] Univ Twente, MESA Res Inst, POB 217, NL-7500 AE Enschede, Netherlands
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中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The transport of ions from aqueous solutions through a stacked Au/alpha-Al2O3/gamma-Al2O3/Au membrane under the influence of a dc potential difference is reported. The membrane shows high cation permselectivity at ionic strengths of similar to10(-3) M at pH 4.3-6.5, which is associated with a combination of anion adsorption and double-layer overlap inside the pores of they-alumina layer. The cation flux can be controlled by ionic strength, dc potential difference and pH.
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页码:187 / +
页数:2
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