Preparation and characterization of RuCl3 - Diamine group functionalized polymer

被引：7

作者：

Duraczynska, D. ^{[1
]}

Drelinkiewicz, A. ^{[1
]}

Serwicka, E. M. ^{[1
]}

Rutkowska-Zbik, D. ^{[1
]}

Bielanska, E. ^{[1
]}

Socha, R. ^{[1
]}

Bukowska, A. ^{[2
]}

Bukowski, W. ^{[2
]}

机构：

[1] Polish Acad Sci, Inst Catalysis & Surface Chem, PL-30239 Krakow, Poland

[2] Rzeszow Univ Technol, Fac Chem, PL-35959 Rzeszow, Poland

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2010年 / 70卷 / 06期

关键词：

Functional polymer; Ruthenium; Hydrogenation; Acetophenone; SUPPORTED PALLADIUM CATALYSTS; GEL-TYPE RESIN; PHYSICOCHEMICAL PROPERTIES; RUTHENIUM NANOPARTICLES; HYDROGENATION; COMPLEXES; APPROXIMATION; ACETOPHENONE; ENERGY; ACIDS;

D O I：

10.1016/j.reactfunctpolym.2010.03.003

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Gel-type resin with diamine functional groups, FCN, was used as a matrix for immobilization of ruthenium complexes. By reacting of RuCl3 with swollen matrix of FCN polymer a series of Ru/FCN composites with various Ru loading (1%, 2%, and 4%) was prepared All the characterization techniques (FT-IR, XRD, SEM, EDS, STEM, XPS, and DSC) proved the participation of functional groups in the coordination of Ru(III). These complexes contained both Cl- and N-ligands in various proportions depending on ruthenium loading in polymer Taking into account the chelating character of N-ligands a hypothetical structure of octahedral Ru(III) complex coordinated to FCN polymer was proposed. 2%Ru/FCN when reduced by NaBH4 exhibited catalytic activity in liquid phase hydrogenation of acetophenone. Higher selectivity in the presence of FCN supported Ru as compared to 2%Ru/Al2O3 catalyst toward 1-phenylethanol was observed. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：382 / 391

页数：10

共 39 条

[1] DENSITY-FUNCTIONAL EXCHANGE-ENERGY APPROXIMATION WITH CORRECT ASYMPTOTIC-BEHAVIOR
BECKE, AD
[J]. PHYSICAL REVIEW A, 1988, 38 (06): : 3098 - 3100
[2] RELATIONSHIPS BETWEEN PHYSICOCHEMICAL PROPERTIES AND CATALYTIC ACTIVITY OF POLYMER-SUPPORTED PALLADIUM CATALYSTS .1. EXPERIMENTAL INVESTIGATIONS
BIFFIS, A
CORAIN, B
CVENGROSOVA, Z
HRONEC, M
JERABEK, K
KRALIK, M
[J]. APPLIED CATALYSIS A-GENERAL, 1995, 124 (02) : 355 - 365
[3] Relationships between physico-chemical properties and catalytic activity of polymer-supported palladium catalysts .2. Mathematical model
Biffis, A
Corain, B
Cvengrosova, Z
Hronec, M
Jerabek, K
Kralik, M
[J]. APPLIED CATALYSIS A-GENERAL, 1996, 142 (02) : 327 - 346
[4] Novel Pt0 catalysts supported on functional resins for the chernoselective hydrogenation of citral to the α, β-unsaturated alcohols geraniol and nerol
Centomo, P
Zecca, M
Lora, S
Vitulli, G
Caporusso, AM
Tropeano, ML
Milone, C
Galvagno, S
Corain, B
[J]. JOURNAL OF CATALYSIS, 2005, 229 (02) : 283 - 297
[5] Catalysis and polymer networks -: the role of morphology and molecular accessibility
Corain, B
Zecca, M
Jerábek, K
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 177 (01) : 3 - 20
[6] Dispersing metal nanoclusters inside functional synthetic resins: scope and catalytic prospects
Corain, B
Kralik, M
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 159 (02) : 153 - 162
[7] Functional gel-type resin based palladium catalysts:: The role of polymer properties in the hydrogenation of the C=C bond of maleic and fumaric acids, the isomers of dicarboxylic acids
Drelinkiewicz, A.
Knapik, A.
Waksmundzka-Gora, A.
Bukowska, A.
Bukowski, W.
Noworol, J.
[J]. REACTIVE & FUNCTIONAL POLYMERS, 2008, 68 (06) : 1059 - 1071
[8] Diamine functionalized gel-type resin as a support for palladium catalysts: Preparation, characterization and catalytic properties in hydrogenation of alkynes
Drelinkiewicz, A.
Knapik, A.
Stanuch, W.
Sobczak, J.
Bukowska, A.
Bukowski, W.
[J]. REACTIVE & FUNCTIONAL POLYMERS, 2008, 68 (12) : 1652 - 1664
[9] DRELINKIEWICZ A, 2004, POLISH J CHEM, V82, P1717
[10] Acetophenone hydrogenation on polymer-palladium catalysts.: The effect of polymer matrix
Drelinkiewicza, A
Waksmundzka, A
Makowski, W
Sobczak, JW
Król, A
Zieba, A
[J]. CATALYSIS LETTERS, 2004, 94 (3-4) : 143 - 156

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