Excess molar Gibbs energies of 2-methylpropan-1-ol with benzene or toluene or o- or m- and p-xylene at 308.15K in terms of an association model

被引：6

作者：

Bhardwaj, U

Maken, S

Singh, KC ^{[1
]}

机构：

[1] Maharshi Dayanand Univ, Dept Chem, Rohtak 124001, Haryana, India

[2] CR State Coll Engn, Dept Appl Sci, Sonepat 131001, India

来源：

FLUID PHASE EQUILIBRIA | 1998年 / 143卷 / 1-2期

关键词：

excess Gibbs energy; association model; Flory contribution term; aromatic hydrocarbon;

D O I：

10.1016/S0378-3812(97)00228-8

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess molar Gibbs energy values for 2-methylpropan-1-ol + benzene or toluene or o- or m-and p-xylene at 308.15 K have been calculated by Barker method from vapour pressure data measured by a static method over the entire range of composition. The excess Gibbs energies for these binary systems are also analysed in terms of the Mecke-Kempter type of association model with a Flory contribution term using two interaction parameters. (C) 1998 Elsevier Science B.V.

引用

页码：153 / 161

页数：9

共 27 条

[1] THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES [J].