Self-assembly and substituent effect of copper(I) complexes with 1,2-bis(2-pyridylethynyl) benzene ligands

被引：16
|
作者：
Kawano, T [1 ]
Kuwana, J [1 ]
Ueda, I [1 ]
机构：
[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2003年 / 76卷 / 04期
关键词：
D O I：
10.1246/bcsj.76.789
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of 1.2-bis(2-pyridylethnyl)benzenes (L1-L5) with copper(I) ions proceeded smoothly to afford mononuclear copper(I) chelate complexes CL1-CL3 or dinuclear copper(I) molecular rectangular boxes. CL4 and CL5, in excellent yields, depending on the size of the substituent. If a ligand with a small substituent was used. the self-assembly of a mononuclear copper(I) chelate complex was achieved. If a ligand with a bulky substituent was used, the self-assembly of dinuclear copper(I) molecular rectangular boxes was achieved. The equilibrium between these two copper(I) complexes Was also observed in solution.
引用
收藏
页码：789 / 797
页数：9
相关论文
共 50 条
  • [21] Self-assembly of three new metal organic coordination networks based on 1,2-bis(imidazol-1yl-methyl)benzene
    Semerci, Fatih
    Yesilel, Okan Zafer
    Yuksel, Fatma
    POLYHEDRON, 2015, 102 : 1 - 7
  • [22] Synthesis and properties of 4,5'-bis(methylthio)-4,5-bis(2-pyridylethynyl)tetrathiafulvalene and its copper complexes
    Isomura, Eigo
    Tokuyama, Ken-ichi
    Nishinaga, Tohru
    Iyoda, Masahiko
    TETRAHEDRON LETTERS, 2007, 48 (33) : 5895 - 5898
  • [23] Complexation Properties and Synthesis of 1,2-Bis(2 ,2' -bipyridinyl)ethylene and 1,2-Bis(2,2' -bipyridinyl)ethane Ligands with Cu(I)
    He Yongbing and Lehn Jean-Marie (Institut Le Bel
    Chemical Research in Chinese Universities, 1990, (03) : 183 - 187
  • [24] [μ-1,2-Bis(diphenylphosphanyl)benzene-κ2P:P′]bis[chloridogold(I)]
    Yoshinari, Nobuto
    Kitani, Naoki
    Tsukuda, Toshiaki
    Konno, Takumi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M121 - U1224
  • [25] Vapochromic and Mechanochromic Tetrahedral Gold(I) Complexes Based on the 1,2-Bis(diphenylphosphino)benzene Ligand
    Osawa, Masahisa
    Kawata, Isao
    Igawa, Satoshi
    Hoshino, Mikio
    Fukunaga, Takeo
    Hashizume, Daisuke
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (40) : 12114 - 12126
  • [26] Coordination dimers constructed from metal(II) halides and the organic ligand 1,2-dimethoxy- 4,5-bis(2-pyridylethynyl)benzene
    Jeffrey E. Fiscus
    Sandra Shotwell
    Ralph C. Layland
    Rachael E. Hipp
    Andrea M. Goforth
    Craig T. Chapman
    Mark D. Smith
    Uwe H. F. Bunz
    Hans-Conrad zur Loye
    Journal of Chemical Crystallography, 2005, 35 : 903 - 912
  • [27] COMPLEXES OF SUBSTITUTED BENZOTHIAZOLES .4. NICKEL(II) COMPLEXES OF THE BIDENTATE BENZOTHIAZOLES 1,2-BIS(2-BENZOTHIAZOLYL)BENZENE AND 1,2-BIS(2-BENZOTHIAZOLYL)ETHANE
    THOMPSON, LK
    RENDELL, JC
    WELLON, GC
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1982, 60 (04): : 514 - 520
  • [28] Surprising Substituent Effects on the Self-Assembly of Helicates from Bis(bipyridyl) BINOL Ligands
    Bunzen, Jens
    Hovorka, Rainer
    Luetzen, Arne
    JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (15): : 5228 - 5236
  • [29] Synthesis and X-ray crystal structure of a complex formed by reaction of 1,2-bis(2′-pyridylethynyl)benzene and mercury(II) chloride
    Barnes, Charles L.
    Bosch, Eric
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2006, 36 (09) : 563 - 566
  • [30] Synthesis and X-ray crystal structure of a complex formed by reaction of 1,2-bis(2′-pyridylethynyl)benzene and mercury(II) chloride
    Charles L. Barnes
    Eric Bosch
    Journal of Chemical Crystallography, 2006, 36 : 563 - 566
12345