Synthesis of novel squaraine dyes and their intermediates

被引：70
作者：
Tatarets, AL
Fedyunyaeva, IA
Terpetschnig, E
Patsenker, LD
机构：
[1] SETA BioMed LLC, Torrance, CA 90505 USA
[2] Natl Acad Sci Ukraine, Inst Single Crystals, UA-61001 Kharkov, Ukraine
来源：
DYES AND PIGMENTS | 2005年 / 64卷 / 02期
关键词：
dyes; synthesis; fluorescence; squaraines;
D O I：
10.1016/j.dyepig.2004.05.003
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
We investigate the reactions of mono-substituted squaraines with CH-acidic nucleophiles, heterocyclic methylene bases and thionating reagents. The reactions of mono-substituted squaraines with malononitrile, cyano- and nitroacetic esters, barbituric acid, 1,3-indanedione, NaHS and P4S10 lead to ring-substituted mono-squaraines. These intermediates are useful for the synthesis of novel squaraine dyes with interesting photophysical properties. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：125 / 134
页数：10
相关论文
共 17 条
[1]   THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].
DEWAR, MJS ;
ZOEBISCH, EG ;
HEALY, EF ;
STEWART, JJP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909
[2]  
Emmelius M., 1989, ANGEW CHEM, V101, P1475
[3]  
HIROO T, Patent No. 2000285978
[4]   Synthesis and characterization of a new class of unsymmetrical squaraine dyes [J].
Keil, D ;
Hartmann, H .
DYES AND PIGMENTS, 2001, 49 (03) :161-179
[5]   Syntheses and properties of functional aminosquarylium dyes [J].
Kim, SH ;
Hwang, SH ;
Kim, JJ ;
Yoon, CM ;
Keum, SR .
DYES AND PIGMENTS, 1998, 37 (02) :145-154
[6]   Synthesis and photostability of functional squarylium dyes [J].
Kim, SH ;
Hwang, SH .
DYES AND PIGMENTS, 1997, 35 (02) :111-121
[7]   SQUARAINE CHEMISTRY - SYNTHESIS, CHARACTERIZATION, AND OPTICAL-PROPERTIES OF A CLASS OF NOVEL UNSYMMETRICAL SQUARAINES - [4-(DIMETHYLAMINO)PHENYL](4'-METHOXYPHENYL)SQUARAINE AND ITS DERIVATIVES [J].
LAW, KY ;
BAILEY, FC .
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (12) :3278-3286
[8]   SQUARAINE CHEMISTRY - SYNTHESIS OF BIS(4-DIMETHYLAMINOPHENYL)SQUARAINE FROM DIALKYL SQUARATES - MECHANISM AND SCOPE OF THE SYNTHESIS [J].
LAW, KY ;
BAILEY, FC .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1986, 64 (12) :2267-2273
[9]   Synthesis and spectral characteristics of some highly soluble squarylium cyanine dyes [J].
Lin, T ;
Peng, BX .
DYES AND PIGMENTS, 1997, 35 (04) :331-338
[10]  
MOTOO T, 1988, J NAT CHEM LAB IND, V23, P381
12