The influence of lithia content on the properties of fluorphlogopite glass-ceramics. II. Microstructure hardness and machinability

被引:44
作者
Henry, J
Hill, RG [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2BP, England
[2] Univ Limerick, Dept Mat Sci & Technol, Limerick, Ireland
关键词
D O I
10.1016/S0022-3093(02)01959-2
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The influence of heat treatment time and temperature on microstructure, hardness and theoretical machinability of glass-ceramics based on 8SiO(2) 3Al(2)O(3) (3 - S)MgO 3MgF(2) (1 - Z)BaOZK(2)OSLi(2)O where lithia was substituted for magnesia and baria for potassia were investigated. Lithia and potassia were found to promote the crystal coarsening of the fluorphlogopite phase and the development of a house of cards microstructure. Hardness was found to decrease slightly on formation of the fluorphlogopite phase, but to decrease markedly on development of the house of cards microstructure. The formation of the house of cards microstructure was promoted by heat treatments close to the observed melting endotherms and was associated with good machinability. Incorporation of lithia was found to suppress the formation of, cordierite in the bulk. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:13 / 30
页数:18
相关论文
共 25 条
[1]   A COMPARATIVE-EVALUATION METHOD OF MACHINABILITY FOR MICA-BASED GLASS-CERAMICS [J].
BAIK, DS ;
NO, KS ;
CHUN, JS ;
YOON, YJ ;
CHO, HY .
JOURNAL OF MATERIALS SCIENCE, 1995, 30 (07) :1801-1806
[2]   Effect of the aspect ratio of mica crystals and crystallinity on the microhardness and machinability of mica glass-ceramics [J].
Baik, DS ;
No, KS ;
Chun, JS ;
Cho, HY .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 1997, 67 (1-3) :50-54
[3]   Study of devitrification of Dicor(R) glass [J].
Bapna, MS ;
Mueller, HJ .
BIOMATERIALS, 1996, 17 (21) :2045-2052
[4]  
Beall G., 1971, ADV NUCL CRYSTALLIZA, P251
[5]   Machinability and brittleness of glass-ceramics [J].
Boccaccini, AR .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 1997, 65 (1-3) :302-304
[6]  
CHEN X, T MAT RES SOC JAPA A, V15, P37
[7]  
CHYUNG CK, 1972, MICROSTRUCTURE MECH, P1167
[8]  
CHYUNG K, 1974, P 10 INT C GLASS, P33
[9]   The influence of calcium to phosphate ratio on the nucleation and crystallization of apatite glass-ceramics [J].
Clifford, A ;
Hill, R ;
Rafferty, A ;
Mooney, P ;
Wood, D ;
Samuneva, B ;
Matsuya, S .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2001, 12 (05) :461-469
[10]   The crystallisation of glasses from the ternary CaF2-CaAl2Si2O8-P2O5 system [J].
Clifford, A ;
Hill, RG ;
Towler, MR ;
Wood, DJ .
JOURNAL OF MATERIALS SCIENCE, 2001, 36 (16) :3955-3961