Nano-12-Tungstophosporic Acid Cesium Salt Synthesized by Ultrasound as Catalyst for Alkylation of Benzene with dec-1-ene

被引:2
作者
Akbay, Elif [1 ]
Demir, Gulberk [1 ]
机构
[1] Anadolu Univ, Dept Chem Engn, TR-26470 Eskisehir, Turkey
关键词
nano; 12-tungstophosporic acid cesium salt; ultrasonic irradiation; alkylation; benzene; dec-1-ene; reusability; LIQUID-PHASE ALKYLATION; 12-TUNGSTOPHOSPHORIC ACID; HETEROPOLY-COMPOUNDS; TOLUENE; NANOPARTICLES; 1-OCTENE; CS2.5H0.5PW12O40; AROMATICS; RESINS; GREEN;
D O I
10.1515/ijcre-2016-0189
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Nano 12-tungtophosphoric acid cesium salt (Cs-TPA) was synthesized under ultrasonic irradiation in nanoscale. The obtained catalyst was characterized by various methods. These analyzes indicate that the chemical structure and crystallinity of nano Cs-TPA remained unchanged while its morphology was found to be different from traditional Cs-TPA which is in irregular shape, becoming spherical with an average particle size of about 50 nm. Nano Cs-TPA was examined in the alkylation of benzene with dec-1-ene, its catalytic activity was remarkably enhanced compared to its original state. The catalyst reusability experiment also showed that the activity of nano Cs-TPA does not decrease even after five reused cycles.
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页数:13
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