Enantioselective palladium catalyzed allylic amination using new chiral pyridine-phosphine ligands

被引：0

作者：

Constantieux, T ^{[1
]}

Brunel, JM ^{[1
]}

Labande, A ^{[1
]}

Buono, G ^{[1
]}

机构：

[1] Ecole Natl Super Synth Proc Ingn Chim Aix Marsei, CNRS, UMR 6516, F-13397 Marseille 20, France

来源：

SYNLETT | 1998年 / 01期

关键词：

allylic amination; palladium; enantioselective; pyridine-phosphine ligands; catalysis;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric palladium catalyzed allylic amination of 5 with various amines has been studied using a new class of chiral pyridine-phosphine ligands. High enantioselectivities of up to 94% ee have been observed using benzylamine, veratrylamine or morpholine as nucleophiles.

引用

页码：49 / +

页数：3

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