Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method

被引：5

作者：

Huang, Yan ^{[1
,2
,3
]}

Zhang, Pilan ^{[1
]}

Hu, Hualei ^{[1
]}

Hu, Danxin ^{[1
]}

Yang, Jie ^{[1
]}

Zhang, Yexin ^{[1
]}

Chen, Chunlin ^{[1
]}

Yang, Yong ^{[1
]}

Zhang, Jian ^{[1
]}

Wang, Lei ^{[1
]}

机构：

[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

RSC ADVANCES | 2019年 / 9卷 / 56期

关键词：

IONIC LIQUIDS; CATALYTIC PERFORMANCE; ALUMINOPHOSPHATE; DEHYDRATION; METAL; CONVERSION; ACID; TRANSFORMATION; OXIDATION; SOLVENT;

D O I：

10.1039/c9ra07217a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A group of CuAPO-5 molecular sieves with trace Cu were successfully synthesized via an ionothermal method and used for fructose dehydration to 5-hydroxymethylfurfural (HMF) in [BMIM]Br ionic liquid. The 0.06-CuAPO-5 sample displayed excellent performance and a HMF yield of 93.8% was obtained, which could be ascribed to the balance between acid strength and mass transfer efficiency. This work demonstrates that the ionothermal synthesized CuAPO-5 molecular sieve was also a good candidate for the efficient production of HMF.

引用

页码：32848 / 32853

页数：6

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