Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method

被引：5
|
作者：
Huang, Yan [1 ,2 ,3 ]
Zhang, Pilan [1 ]
Hu, Hualei [1 ]
Hu, Danxin [1 ]
Yang, Jie [1 ]
Zhang, Yexin [1 ]
Chen, Chunlin [1 ]
Yang, Yong [1 ]
Zhang, Jian [1 ]
Wang, Lei [1 ]
机构：
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
RSC ADVANCES | 2019年 / 9卷 / 56期
关键词：
IONIC LIQUIDS; CATALYTIC PERFORMANCE; ALUMINOPHOSPHATE; DEHYDRATION; METAL; CONVERSION; ACID; TRANSFORMATION; OXIDATION; SOLVENT;
D O I：
10.1039/c9ra07217a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A group of CuAPO-5 molecular sieves with trace Cu were successfully synthesized via an ionothermal method and used for fructose dehydration to 5-hydroxymethylfurfural (HMF) in [BMIM]Br ionic liquid. The 0.06-CuAPO-5 sample displayed excellent performance and a HMF yield of 93.8% was obtained, which could be ascribed to the balance between acid strength and mass transfer efficiency. This work demonstrates that the ionothermal synthesized CuAPO-5 molecular sieve was also a good candidate for the efficient production of HMF.
引用
收藏
页码：32848 / 32853
页数：6
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