The importance of agitation and fill volume in small scale scientific microwave reactors

被引：26

作者：

Moseley, Jonathan D. ^{[1
]}

Lenden, Philip ^{[1
]}

Thomson, Anthony D. ^{[1
]}

Gilday, John P. ^{[1
]}

机构：

[1] Avlon Works, Bristol BS10 7ZE, Avon, England

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 35期

关键词：

ORGANIC-SYNTHESIS; ASSISTED REACTIONS; REARRANGEMENT; OVENS;

D O I：

10.1016/j.tetlet.2007.06.147

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of agitation and fill volume in a microwave tube on the rate of homogenous reaction solutions under both stirred and unstirred conditions is reported. Significant increases in rate are found in two different microwave instruments when the homogenous reaction mixture is unstirred. These results have significant implications for the continuing use of domestic or kitchen type microwaves in synthetic applications; and in scientific microwaves where stirring may be compromised, for example in the presence of heavy slurries or viscous liquids. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：6084 / 6087

页数：4

共 29 条

[1]

[Anonymous], UNPUB

[2] MICROWAVE-ASSISTED ORGANIC-REACTIONS [J].