Synthesis, spectroscopic and structural characterization of new complex of ruthenium(II) with Hmtpo ligand

被引：9

作者：

Malecki, J. G. ^{[1
]}

Kruszynski, R. ^{[2
]}

机构：

[1] Silesian Univ, Inst Chem, Dept Inorgan & Coordinat Chem, PL-40006 Katowice, Poland

[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland

来源：

POLYHEDRON | 2010年 / 29卷 / 03期

关键词：

Ruthenium hydride carbonyl complexes; 7-Hydroxy-5-methyl[1,2.4]triazolo[1,5-a]pyrimidine; X-ray structure; UV-Vis; DFT; TD-DFT; DENSITY-FUNCTIONAL THEORY; TRANSFER EXCITED-STATES; HYDROGEN-BONDS; EXCHANGE; CHEMISTRY; SPECTRUM;

D O I：

10.1016/j.poly.2009.12.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [(PPh3)(2)RuHCl(CO)(Hmtpo)] complex has been prepared and studied by IR, NMR, UV-VIS spectroscopy and X-ray crystallography. The complex was prepared in reactions of [RuHCl(CO)(PPh3)(3)] with 7-hydroxy-5-methyl[1,2,4]triazolo[1,5-a]pyrimidine in methanol The electronic structure and UV-Vis spectrum of the obtained compound have been calculated using the TD-DFT method. (C) 2009 Elsevier Ltd All rights reserved.

引用

页码：1023 / 1028

页数：6

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