Theoretical investigation of optical and EPR spectra for nickel (II) in ANSH crystal

被引：8
作者：
Feng, W. -L. [1 ]
Chen, T. -H. [2 ]
Wang, L. -J [3 ]
Chen, J. -J [2 ]
机构：
[1] Chongqing Inst Technol, Dept Appl Phys, Chongqing 400054, Peoples R China
[2] China W Normal Univ, Dept Phys & Elect Informat, Nanchong 637002, Peoples R China
[3] Neijiang Normal Coll, Dept Phys & Elect Informat Engn, Neijiang 641112, Sichuan, Peoples R China
来源：
OPTIK | 2010年 / 121卷 / 04期
关键词：
Optical properties; Local lattice structure; ANSH crystal; Ni(2+); ELECTRON-PARAMAGNETIC-RESONANCE; LOCAL LATTICE STRUCTURE; IONS; PARAMETERS; HEXAHYDRATE; SULPHATE; V3+;
D O I：
10.1016/j.ijleo.2008.07.015
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Based on the semi-self-consistent field (semi-SCF) d-orbital theory and point charge model, we have Studied the optical spectra by the complete diagonalizing (of energy matrix) method (CDM) and electronic paramagnetic resonance (EPR.) spectra by the Perturbation theory method (PTM) for Ni(2+) center in the ammonium nickel(II) Sulfate hexahydrate [(NH(4))(2)Ni(SO(4))center dot 6H(2)O, abbr. ANSH] crystal. The Structural parameters of the ANSH crystal have been obtained and theoretical results agree well with the experimental findings. (C) 2008 Elsevier GmbH. All rights reserved.
引用
收藏
页码：362 / 365
页数：4
相关论文
共 17 条
  • [1] ORTHORHOMBIC CRYSTALLINE FIELD THEORY OF NI2+ .6H2O COMPLEX
    BOSE, A
    CHATTERJEE, R
    [J]. PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1963, 82 (525): : 23 - &
  • [2] HIGH-ORDER PERTURBATION FORMULAS OF THE SPIN-HAMILTONIAN PARAMETERS FOR THE GROUND-STATE A-3(2)(F) OF D8 IONS IN RHOMBIC SYMMETRY
    CHEN, JJ
    ZHAO, MG
    [J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1987, 143 (02): : 647 - 653
  • [3] Substitutional site and defect structure of Ni2+ in LiNbO3 crystal studied from the optical and electron paramagnetic resonance spectra
    Feng, Wen-Lin
    Wu, Xiao-Xuan
    Zheng, Wen-Chen
    [J]. RADIATION EFFECTS AND DEFECTS IN SOLIDS, 2008, 163 (01): : 29 - 34
  • [4] Feng WL, 2006, Z NATURFORSCH A, V61, P691
  • [5] Investigations of the optical and EPR spectra of V3+ ions in C(NH2)3Al(SO4)2 • 6H2O crystal
    Feng, Wen-Lin
    Wu, Xiao-Xuan
    Zheng, Wen-Chen
    [J]. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2006, 243 (08): : 1881 - 1884
  • [6] CRYSTAL STRUCTURE OF AMMONIUM NICKEL SULPHATE HEXAHYDRATE (NH4)2NI(SO4)2.6H2O
    GRIMES, NW
    WEBB, MW
    KAY, HF
    [J]. ACTA CRYSTALLOGRAPHICA, 1963, 16 (08): : 823 - &
  • [7] THE ABSORPTION SPECTRA OF SOLID HYDRATED NICKEL SULPHATE
    HARTMANN, H
    MULLER, H
    [J]. DISCUSSIONS OF THE FARADAY SOCIETY, 1958, (26): : 49 - 52
  • [8] Jiao ZY, 2006, EUR PHYS J B, V53, P297, DOI 10.1140/epjb/e2006-00370-5
  • [9] ZERO FIELD SPLITTINGS OF T23 CUBIC TERMS
    MACFARLANE, RM
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (06) : 2066 - +
  • [10] CRYSTAL STRUCTURE OF TUTTONS SALTS .2. MAGNESIUM AMMONIUM SULFATE HEXAHYDRATE + NICKEL AMMONIUM SULFATE HEXAHYDRATE
    MONTGOMERY, H
    LINGAFELTER, EC
    [J]. ACTA CRYSTALLOGRAPHICA, 1964, 17 (11): : 1478 - &
12