Adducts of Triallylborane with Ammonia and Aliphatic Amines as Stoichiometric Allylating Agents for Aminoallylation Reaction of Carbonyl Compounds

被引：10
作者：
Kuznetsov, Nikolai Yu. [1 ]
Tikhov, Rabdan M. [1 ]
Strelkova, Tatiana V. [1 ]
Bubnov, Yuri N. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov 28, Moscow 119991, Russia
来源：
ORGANIC LETTERS | 2018年 / 20卷 / 12期
基金：
俄罗斯科学基金会;
关键词：
ASYMMETRIC-SYNTHESIS; ORGANOBORON COMPOUNDS; HOMOALLYLIC AMINES; ORGANOMETALLIC REAGENTS; CHIRAL SYNTHESIS; ALLYLBORATION; ALPHA; IMINES; ACIDS; ALCOHOLS;
D O I：
10.1021/acs.orglett.8b01317
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Triallylborane-amines adducts are effective stoichiometric allylating agents in the aminoallylation reaction of carbonyl compounds in methanol. Moreover, copper-catalyzed diastereoselective allylation of Ellman's imine was achieved with triallylborane-methylamine adduct.
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页码：3549 / 3552
页数：4
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