The anionic thia-Fries rearrangement of aryl triflates

被引：59

作者：

Charmant, JPH

Dyke, AM

Lloyd-Jones, GC

机构：

[1] Bristol Ctr Organomet Catalysis, Bristol, Avon, England

[2] Univ Bristol, Sch Chem, Struct Chem Lab, Bristol, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 03期

关键词：

D O I：

10.1039/b210648e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aryl triflates undergo LDA-mediated rearrangement to generate o-hydroxyaryl trifluoromethylsulfones. In some cases, partitioning between rearrangement and aryne generation can be controlled.

引用

页码：380 / 381

页数：2

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