Calmodulin methionine residues are targets for one-electron oxidation by hydroxyl radicals:: formation of S ∴N three-electron bonded radical complexes

被引：22

作者：

Nauser, T ^{[1
]}

Jacoby, M

Koppenol, WH

Squier, TC

Schöneich, C

机构：

[1] Swiss Fed Inst Technol, Inorgan Chem Lab, CH-8093 Zurich, Switzerland

[2] Pacific NW Natl Lab, Richland, WA USA

[3] Univ Kansas, Dept Pharmaceut Chem, Lawrence, KS 66045 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 05期

关键词：

D O I：

10.1039/b414687e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-electron oxidation of calmodulin, studied on the microsecond timescale by pulse radiolysis, leads to methionine sulfide radical cations, which complex to adjacent amide groups to form three-electron bonded intermediates.

引用

页码：587 / 589

页数：3

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