Construction of Heptagon-Containing Molecular Nanocarbons

被引：152

作者：

Chaolumen ^{[1
]}

Stepek, Iain A. ^{[1
]}

Yamada, Keigo E. ^{[2
]}

Ito, Hideto ^{[2
]}

Itami, Kenichiro ^{[1
,2
,3
]}

机构：

[1] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[3] Acad Sinica, Inst Chem, Taipei 115, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2021年 / 60卷 / 44期

关键词：

defects; electronic materials; heptagons; nanocarbons; polycyclic aromatic rocarbons; POLYCYCLIC AROMATIC-HYDROCARBONS; HEXA-PERI-HEXABENZOCORONENE; WARPED NANOGRAPHENE; CARBON NANOTUBES; SCHOLL REACTION; BUILDING-BLOCK; AZULENE; GRAPHENE; NAPHTHALENE; EFFICIENT;

D O I：

10.1002/anie.202100260

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular nanocarbons containing heptagonal rings have attracted increasing interest due to their dynamic behavior, electronic properties, aromaticity, and solid-state packing. Heptagon incorporation can not only induce negative curvature within nanocarbon scaffolds, but also confer significantly altered properties through interaction with adjacent non-hexagonal rings. Despite the disclosure of several beautiful examples in recent years, synthetic strategies toward heptagon-embedded molecular nanocarbons remain relatively limited due to the intrinsic challenges of heptagon formation and incorporation into polyarene frameworks. In this Review, recent advances in solution-mediated and surface-assisted synthesis of heptagon-containing molecular nanocarbons, as well as the intriguing properties of these frameworks, will be discussed.

引用

页码：23508 / 23532

页数：25

共 230 条

[41] Enantiopure distorted ribbon-shaped nanographene combining two-photon absorption-based upconversion and circularly polarized luminescence [J].

Cruz, Carlos M. ;

Marquez, Irene R. ;

Mariz, Ines F. A. ;

Blanco, Victor ;

Sanchez-Sanchez, Carlos ;

Sobrado, Jesus M. ;

Martin-Gago, Jose A. ;

Cuerva, Juan M. ;

Macoas, Ermelinda ;

Campana, Araceli G. .

CHEMICAL SCIENCE, 2018, 9 (16) :3917-3924

[42]

Cruz CM, 2018, Angew. Chem, V130, P14998

[43] Functionalization of Graphene for Efficient Energy Conversion and Storage [J].

Dai, Liming .

ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (01) :31-42

[44] Toward Singlet-Triplet Bistable Nonalternant Kekule Hydrocarbons: Azulene-to-Naphthalene Rearrangement [J].

Das, Soumyajit ;

Wu, Jishan .

ORGANIC LETTERS, 2015, 17 (23) :5854-5857

[45] CRYSTAL-STRUCTURE AND BONDING OF ORDERED C60 [J].

DAVID, WIF ;

IBBERSON, RM ;

MATTHEWMAN, JC ;

PRASSIDES, K ;

DENNIS, TJS ;

HARE, JP ;

KROTO, HW ;

TAYLOR, R ;

WALTON, DRM .

NATURE, 1991, 353 (6340) :147-149

[46] Topological line defects in graphene for applications in gas sensing [J].

de Souza, Fabio A. L. ;

Amorim, Rodrigo G. ;

Prasongkit, Jariyanee ;

Scopel, Wanderla L. ;

Scheicher, Ralph H. ;

Rocha, Alexandre R. .

CARBON, 2018, 129 :803-808

[47] Naphthyl-Fused Phosphepines: Luminescent Contorted Polycyclic P-Heterocycles [J].

Delouche, Thomas ;

Mokrai, Reka ;

Roisnel, Thierry ;

Tondelier, Denis ;

Geffroy, Bernard ;

Nyulaszi, Laszlo ;

Benko, Zoltan ;

Hissler, Muriel ;

Bouit, Pierre-Antoine .

CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (08) :1856-1863

[48] Breaking the Kasha Rule for More Efficient Photochemistry [J].

Demchenko, Alexander P. ;

Tomin, Vladimir I. ;

Chou, Pi-Tai .

CHEMICAL REVIEWS, 2017, 117 (21) :13353-13381

[49] Induced magnetic ordering by proton irradiation in graphite -: art. no. 227201 [J].

Esquinazi, P ;

Spemann, D ;

Höhne, R ;

Setzer, A ;

Han, KH ;

Butz, T .

PHYSICAL REVIEW LETTERS, 2003, 91 (22)

[50] Nanoribbons with Nonalternant Topology from Fusion of Polyazulene: Carbon Allotropes beyond Graphene [J].

Fan, Qitang ;

Martin-Jimenez, Daniel ;

Ebeling, Daniel ;

Krug, Claudio K. ;

Brechmann, Lea ;

Kohlmeyer, Corinna ;

Hilt, Gerhard ;

Hieringer, Wolfgang ;

Schirmeisen, Andre ;

Gottfried, J. Michael .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (44) :17713-17720

← 1 2 3 4 5 6 7 8 9 10 →