Choline chloride-lactic acid deep eutectic solvent for delignification and nanocellulose production of moso bamboo

被引:136
作者
Liu, Qian [1 ]
Yuan, Tao [1 ]
Fu, Qin-jin [1 ]
Bai, Yuan-yuan [2 ]
Peng, Feng [1 ]
Yao, Chun-li [1 ]
机构
[1] Beijing Forestry Univ, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China
[2] China Natl Pulp & Paper Res Inst Co Ltd, Natl Engn Lab Pulp & Paper, Beijing 100102, Peoples R China
基金
国家重点研发计划;
关键词
Pretreatment; Deep eutectic solvent; Bamboo; Delignification; Nanofibers; LIGNOCELLULOSIC BIOMASS; RICE STRAW; CELLULOSE NANOCRYSTALS; PRETREATMENT; LIGNIN; WOOD; NANOFIBRILLATION; CARBOHYDRATE; EXTRACTION; PYROLYSIS;
D O I
10.1007/s10570-019-02726-0
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
A facile, green and economical method for the high-efficiency utilization and functionalization of bamboo fiber could significantly improve the development of biomass industries. Here, we demonstrated a deep eutectic solvent, which formed from choline chloride (ChCl) and lactic acid (LC), as pretreating agent to delignify moso bamboo (Phyllostachys pubescens) and produce nanocellulose. The results showed that most of the lignin was efficiently removed (94.39%) and 91% of the cellulose was recovered after the moso bamboo was pretreated with ChCl-LC at 120 degrees C for 3 h with a solid-to-liquid ratio of 1:25. Furthermore, nanofibers with widths of 20-80 nm were successfully prepared from pretreated fibers after a simple mechanical process. SEM and AFM images showed that they have excellent aspect ratio. In addition, the obtained nanofibers could be used to fabricate strong films which feature a high tensile strength ranged from 163 to 213 MPa.
引用
收藏
页码:9447 / 9462
页数:16
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