Preparation of aqueous graphene suspensions by ultrasonication in the presence of a fluorine-containing surfactant

被引:7
作者
Samoilov, V. M. [1 ]
Nikolaeva, A. V. [1 ]
Danilov, E. A. [1 ]
Erpuleva, G. A. [1 ]
Trofimova, N. N. [1 ]
Abramchuk, S. S. [2 ]
Ponkratov, K. V. [3 ]
机构
[1] State Res Inst Struct Graphite Mat, Elektrodnaya Ul 2, Moscow 111141, Russia
[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
[3] OOO Renishaw, Moscow 115477, Russia
关键词
LIQUID-PHASE EXFOLIATION; LARGE-AREA; GRAPHITE; FILMS; OXIDE; TRANSPARENT;
D O I
10.1134/S0020168515010161
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Concentrated suspensions of few-layer graphene particles have been prepared via natural graphite exfoliation by ultrasonic processing in the presence of a fluorine-containing surfactant and with no surfactant. The kinetics of the process and the properties of the products have been studied using laser diffraction, X-ray diffraction, transmission electron microscopy, electron diffraction, and Raman spectroscopy. We have obtained aqueous suspensions containing up to 95% few-layer graphene with a concentration of 6 mg/mL.
引用
收藏
页码:98 / 105
页数:8
相关论文
共 50 条
[1]   STRUCTURAL TRANSFORMATIONS INDUCED IN GRAPHITE BY GRINDING - ANALYSIS OF 002-X-RAY DIFFRACTION LINE-PROFILES [J].
ALADEKOMO, JB ;
BRAGG, RH .
CARBON, 1990, 28 (06) :897-906
[2]  
Allen T, 1990, Powder Technology Series
[3]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[4]   Liquid-Phase Exfoliation of Graphite Towards Solubilized Graphenes [J].
Bourlinos, Athanasios B. ;
Georgakilas, Vasilios ;
Zboril, Radek ;
Steriotis, Theodore A. ;
Stubos, Athanasios K. .
SMALL, 2009, 5 (16) :1841-1845
[5]   GRAPHITE INTERPLANAR BONDING - ELECTRONIC DELOCALIZATION AND VAN-DER-WAALS INTERACTION [J].
CHARLIER, JC ;
GONZE, X ;
MICHENAUD, JP .
EUROPHYSICS LETTERS, 1994, 28 (06) :403-408
[6]  
Cheung W., 2010, SMALL, V6, P1071
[7]   Noncovalent functionalization of graphene with end-functional polymers [J].
Choi, Eun-Young ;
Han, Tae Hee ;
Hong, Jihyun ;
Kim, Ji Eun ;
Lee, Sun Hwa ;
Kim, Hyun Wook ;
Kim, Sang Ouk .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (10) :1907-1912
[8]   Synthesis of Graphene and Its Applications: A Review [J].
Choi, Wonbong ;
Lahiri, Indranil ;
Seelaboyina, Raghunandan ;
Kang, Yong Soo .
CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES, 2010, 35 (01) :52-71
[9]   Graphene via sonication assisted liquid-phase exfoliation [J].
Ciesielski, Artur ;
Samori, Paolo .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (01) :381-398
[10]   Liquid Exfoliation of Defect-Free Graphene [J].
Coleman, Jonathan N. .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (01) :14-22