Oxidation of Ethylbenzene Using Nickel Oxide Supported Metal Organic Framework Catalyst

被引：35

作者：

Peng, Mei Mei ^{[1
]}

Jeon, Ung Jin ^{[1
]}

Ganesh, Mani ^{[1
]}

Aziz, Abidov ^{[1
]}

Vinodh, Rajangam ^{[1
]}

Palanichamy, Muthiahpillai ^{[1
]}

Jang, Hyun Tae ^{[1
]}

机构：

[1] Hanseo Univ, Dept Chem Engn, Chungcheongnam Do 356706, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2014年 / 35卷 / 11期

关键词：

Solid catalyst; MOFs; Ni-MOF-5; Oxidation reaction; Ethylbenzene; HYDROGEN ADSORPTION; MOF-5; NANOPARTICLES; EQUILIBRIUM; KINETICS; DESIGN; GUEST; CU;

D O I：

10.5012/bkcs.2014.35.11.3213

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal organic framework-supported Nickel nanoparticle (Ni-MOF-5) was successfully synthesized using a simple impregnation method. The obtained solid acid catalyst was characterized by Powder X ray diffraction (XRD), scanning electron microscopy (SEM), nitrogen adsorption-desorption and thermogravimetric analysis (TGA). The catalyst was highly crystalline with good thermodynamic stability (up to 400 degrees C) and high surface area (699 m(2)g(-1)). The catalyst was studied for the oxidation of ethyl benzene, and the results were monitored via gas chromatography (GC) and found that the Ni-MOF-5 catalyst was highly effective for ethyl benzene oxidation. The conversion of ethyl benzene and the selectivity for acetophenone were 55.3% and 90.2%, respectively.

引用

页码：3213 / 3218

页数：6

共 46 条

[1] Cation-Triggered Drug Release from a Porous Zinc-Adeninate Metal-Organic Framework [J].

An, Jihyun ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (24) :8376-+

[2] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[3] [Cu(H2btec)(bipy)]∞: a novel metal organic framework (MOF) as heterogeneous catalyst for the oxidation of olefins [J].

Brown, Kareen ;

Zolezzi, Santiago ;

Aguirre, Pedro ;

Venegas-Yazigi, Diego ;

Paredes-Garcia, Veronica ;

Baggio, Ricardo ;

Novak, Miguel A. ;

Spodine, Evgenia .

DALTON TRANSACTIONS, 2009, (08) :1422-1427

[4] A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation [J].

Cho, So-Hye ;

Ma, Baoqing ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. ;

Albrecht-Schmitt, Thomas E. .

CHEMICAL COMMUNICATIONS, 2006, (24) :2563-2565

[5]

Dongmei J., 2010, J CATAL, V270, P26

[6]

Edson V. P., 2009, MEMBRANE SCI, V328, P165

[7] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[8] Palladium nanoparticles supported on MOF-5: A highly active catalyst for a ligand- and copper-free Sonogashira coupling reaction [J].

Gao, Shuixia ;

Zhao, Nan ;

Shu, Mouhai ;

Che, Shunai .

APPLIED CATALYSIS A-GENERAL, 2010, 388 (1-2) :196-201

[9]

Guofeng Z., 2013, APPL CATAL B-ENVIRON, V140-141, P249

[10] Flexible porous metal-organic frameworks for a controlled drug delivery [J].

Horcajada, Patricia ;

Serre, Christian ;

Maurin, Guillaume ;

Ramsahye, Naseem A. ;

Balas, Francisco ;

Vallet-Regi, Maria ;

Sebban, Muriel ;

Taulelle, Francis ;

Ferey, Gerard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (21) :6774-6780

← 1 2 3 4 5 →