Metal-Organic Frameworks in Agriculture

被引:95
|
作者
Rojas, Sara [1 ]
Rodriguez-Dieguez, Antonio [1 ]
Horcajada, Patricia [2 ]
机构
[1] Univ Granada, Dept Inorgan Chem, Biochem & Elect Sensing Technol Grp, E-18071 Granada, Spain
[2] IMDEA Energy, Adv Porous Mat Unit APMU, Madrid 28935, Spain
关键词
metal-organic frameworks; agrochemicals; controlled release; selective adsorption and degradation; sensing; SOLID-PHASE EXTRACTION; PERFORMANCE LIQUID-CHROMATOGRAPHY; ORGANOPHOSPHORUS PESTICIDES; ENVIRONMENTAL WATER; GRAPHENE OXIDE; ADSORPTION CAPACITY; AQUEOUS-SOLUTION; SULFONYLUREA HERBICIDES; TRIAZINE HERBICIDES; SENSITIVE DETECTION;
D O I
10.1021/acsami.2c00615
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Agrochemicals, which are crucial to meet the world food qualitative and quantitative demand, are compounds used to kill pests (insects, fungi, rodents, or unwanted plants). Regrettably, there are some important issues associated with their widespread and extensive use (e.g., contamination, bioaccumulation, and development of pest resistance); thus, a reduced and more controlled use of agrochemicals and thorough detection in food, water, soil, and fields are necessary. In this regard, the development of new functional materials for the efficient application, detection, and removal of agrochemicals is a priority. Metal-organic frameworks (MOFs) with exceptional sorptive, recognition capabilities, and catalytical properties have very recently shown their potential in agriculture. This Review emphasizes the recent advances in the use of MOFs in agriculture through three main views: environmental remediation, controlled agrochemical release, and detection of agrochemicals.
引用
收藏
页码:16983 / 17007
页数:25
相关论文
共 50 条
  • [1] Covalent Metal-Organic Frameworks: Fusion of Covalent Organic Frameworks and Metal-Organic Frameworks
    Wei, Rong-Jia
    Luo, Xiao
    Ning, Guo-Hong
    Li, Dan
    ACCOUNTS OF CHEMICAL RESEARCH, 2025, 58 (05) : 746 - 761
  • [2] Metal-organic macrocycles, metal-organic polyhedra and metal-organic frameworks
    Prakash, M. Jaya
    Lah, Myoung Soo
    CHEMICAL COMMUNICATIONS, 2009, (23) : 3326 - 3341
  • [3] Metal-organic frameworks
    James, SL
    CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) : 276 - 288
  • [4] Metal-organic frameworks
    Birkett, Jim
    CHEMICAL & ENGINEERING NEWS, 2017, 95 (30) : 2 - 2
  • [5] Metal-Organic Frameworks and Metal-Organic Cages - A Perspective
    Pilgrim, Ben S.
    Champness, Neil R.
    CHEMPLUSCHEM, 2020, 85 (08): : 1842 - 1856
  • [6] Teaching Metal-Organic Frameworks to Conduct: Ion and Electron Transport in Metal-Organic Frameworks
    Kharod, Ruby A.
    Andrews, Justin L.
    Dinc, Mircea
    ANNUAL REVIEW OF MATERIALS RESEARCH, 2022, 52 : 103 - 128
  • [7] Substitution reactions in metal-organic frameworks and metal-organic polyhedra
    Han, Yi
    Li, Jian-Rong
    Xie, Yabo
    Guo, Guangsheng
    CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) : 5952 - 5981
  • [8] Metal-Ion Metathesis in Metal-Organic Frameworks: A Synthetic Route to New Metal-Organic Frameworks
    Kim, Yonghwi
    Das, Sunirban
    Bhattacharya, Saurav
    Hong, Soonsang
    Kim, Min Gyu
    Yoon, Minyoung
    Natarajan, Srinivasan
    Kim, Kimoon
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (52) : 16642 - 16648
  • [9] Metal-Organic Frameworks as Electrocatalysts
    Peng, Yong
    Sanati, Soheila
    Morsali, Ali
    Garcia, Hermenegildo
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (09)
  • [10] Multivariate metal-organic frameworks
    Aasif Helal
    Zain H.Yamani
    Kyle E.Cordova
    Omar M.Yaghi
    NationalScienceReview, 2017, 4 (03) : 296 - 298