Synthesis and catalytic activity of ionic palladium N-heterocyclic carbene complexes

被引：4

作者：

Yasar, Sedat ^{[1
]}

Akkoc, Mitat ^{[1
]}

Ozdemir, Namik ^{[2
]}

Ozdemir, Ismail ^{[1
]}

机构：

[1] Inonu Univ, Fac Sci & Art, Dept Chem, Malatya, Turkey

[2] Ondokuz Mayis Univ, Fac Educ, Dept Math & Sci Educ, Samsun, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2019年 / 43卷 / 06期

关键词：

Ionic palladium complex; N-heterocyclic carbene; C-C bond formation; anionic palladium species; Suzuki-Miyaura cross-coupling reactions; CROSS-COUPLING REACTIONS; SUZUKI-MIYAURA; PHENYLBORONIC ACID; ARYL CHLORIDES; WATER; LIGANDS; BULKY; PD;

D O I：

10.3906/kim-1907-74

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of 3 benzimidazole-based ionic Pd(II)-NHC complexes (NHC: N-heterocyclic carbene) is presented. The structures of the complexes are as follows: [NHC-PdBr3](-) [NHC](+). The ionic palladium(II)-NHC complexes were synthesized in high yields and were fully characterized by nuclear magnetic resonance spectroscopy, X-ray diffraction, LC-MS/MS, and elemental analysis. These complexes have been identified as active catalysts in Suzuki-Miyaura reactions in a solution of 2-propanol and water at room temperature for different aryl bromides.

引用

页码：1622 / +

页数：20

共 50 条

[1] Palladium(II)-N-heterocyclic carbene complexes: synthesis, characterization and catalytic application
Cekirdek, Suzan
Yasar, Sedat
Ozdemir, Ismail
APPLIED ORGANOMETALLIC CHEMISTRY, 2014, 28 (06) : 423 - 431
[2] Palladium N-heterocyclic carbene complexes: Synthesis, characterization and catalytic properties in amination
Ozdemir, Ismail
Demir, Serpil
Sahin, Onur
Buyukgungor, Orhan
Cetinkaya, Bekir
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (10-11) : 1555 - 1560
[3] Synthesis, structural characterization and catalytic activity of two N-heterocyclic carbene-phosphine palladium(II) complexes
Xu, Chen
Hao, Xin-Qi
Li, Zhen
Dong, Xin-Ming
Duan, Lu-Meng
Wang, Zhi-Qiang
Ji, Bao-Ming
Song, Mao-Ping
INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 17 : 34 - 37
[4] Acyclic Palladium(II)-N-heterocyclic Carbene Metallacrown Ether Complexes: Synthesis, Structure and Catalytic Activity
Zhang Weixi
Zhang Xiaoqin
Luo Meiming
CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (07) : 1423 - 1428
[5] Tripodal N-Heterocyclic Carbene Complexes of Palladium and Copper: Syntheses, Characterization, and Catalytic Activity
Ellul, Charles E.
Reed, Graham
Mahon, Mary F.
Pascu, Sofia I.
Whittlesey, Michael K.
ORGANOMETALLICS, 2010, 29 (18) : 4097 - 4104
[6] N-Heterocyclic Carbene-Palladium(II) Complexes with Acridine Ligand: Synthesis, Characterization and Catalytic Applications
Wang, Tao
Xu, Kai
Meng, Tuanjie
Zhang, An'an
Wang, Hongyu
Shen, Sisi
Liu, Lantao
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (07) : 1794 - 1799
[7] Butylene linked palladium N-heterocyclic carbene complexes: Synthesis and catalytic properties
Demir, Serpil
Ozdemir, Ismail
Arslan, Hakan
VanDerveer, Don
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (13) : 2589 - 2593
[8] Potentially Hemilabile N-Heterocyclic Carbene Palladium Complexes: Synthesis and Catalytic Applications
Gu, Shaojin
Chen, Chao
Qiu, Huayu
Chen, Wanzhi
CURRENT ORGANIC CHEMISTRY, 2011, 15 (18) : 3291 - 3308
[9] Synthesis and catalytic activity of pyrazolyl-functionalized N-heterocyclic carbene palladium complexes
Cheng, Cai-Hong
Xu, Jia-Ru
Song, Hai-Bin
Tang, Liang-Fu
TRANSITION METAL CHEMISTRY, 2014, 39 (02) : 151 - 157
[10] Synthesis, characterization and catalytic activity of novel N-heterocyclic carbene-palladium complexes
Dogan, Oznur
Gurbuz, Nevin
Ozdemir, Ismail
Cetinkaya, Bekir
Sahin, Onur
Buyukgungor, Orhan
DALTON TRANSACTIONS, 2009, (35) : 7087 - 7093

← 1 2 3 4 5 →