Tin dioxide/carbon nanotube composites with high uniform SnO2 loading as anode materials for lithium ion batteries

被引:111
作者
Du, Guodong [1 ]
Zhong, Chao [1 ]
Zhang, Peng [1 ]
Guo, Zaiping [1 ,2 ]
Chen, Zhixin [2 ]
Liu, Huakun [1 ]
机构
[1] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
[2] Univ Wollongong, Sch Mech Mat & Mechatron Engn, Wollongong, NSW 2522, Australia
基金
澳大利亚研究理事会;
关键词
Tin oxide; Solvothermal; Carbon nanotube; Composite; Lithium ion batteries; WALLED CARBON NANOTUBES; TEMPLATE-FREE SYNTHESIS; HIGH-CAPACITY; OXIDE; NANOSTRUCTURES; MICROSPHERES; FABRICATION;
D O I
10.1016/j.electacta.2009.12.031
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
SnO2/multi-walled carbon nanotube (MWCNT) composites were prepared by the solvothermal method and subsequent heat treatment at 360 degrees C. The samples were characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Results on the higher SnO2 content composite sample indicate that a uniform layer of SnO2 nanocrystals with crystal size around 5 nm was deposited on the surface of the carbon nanotubes. The composite demonstrates a reversible lithium storage capacity of 709.9 mAh g(-1) at the first cycle and excellent cyclic retention up to 100 cycles as anode for lithium ion batteries. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2582 / 2586
页数:5
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