Influence of interaction between a substituent and the benzene ring on the hydrogenation rate of nitrobenzene and its partial reduction products

被引：0

作者：

Kochetova, LB ^{[1
]}

Klyuev, MV ^{[1
]}

机构：

[1] Ivanovo State Univ, Ivanovo 153377, Russia

来源：

PETROLEUM CHEMISTRY | 2000年 / 40卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Geometric parameters (bond lengths and bond angles) of nitrobenzene, nitrosobenzene, phenylhydroxylamine, azoxybenzene, azobenzene, hydrazobenzene, and aniline were calculated in the MNDO approximation. From these data, the magnitude of interaction between the substituents and the benzene ring was evaluated, which correlates with the rate constant for hydrogenation of these compounds over a Pd/C catalyst.

引用

页码：341 / 343

页数：3