A transparent and Pt-free all-carbon nanocomposite counter electrode catalyst for efficient dye sensitized solar cells

被引:41
作者
Gurulakshmi, M. [1 ]
Meenakshamma, A. [1 ]
Susmitha, K. [1 ]
Charanadhar, N. [2 ]
Srikanth, V. V. S. S. [2 ]
Babu, S. Narendra [3 ]
Subbaiah, Y. P. Venkata [1 ]
Venkateswarlu, Katta [4 ]
Raghavender, M. [1 ]
机构
[1] Yogi Vemana Univ, Dept Phys, Kadapa 516005, India
[2] Univ Hyderabad, Sch Engn Sci & Technol, Hyderabad 500046, India
[3] Osmania Univ, Dept Phys, Hyderabad 500007, India
[4] Yogi Vemana Univ, Dept Chem, Kadapa 516005, India
关键词
Cost effective composite counter electrode; Transparent DSSC module; Reduced graphene oxide; SWCNH; Dye sensitized solar cell; REDUCED GRAPHENE OXIDE; HIGH-PERFORMANCE; DEOXYGENATION; TEMPERATURE; REDUCTION; DEVICES;
D O I
10.1016/j.solener.2019.09.081
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Recently, substantial focus has made in the development of cost effective Pt-free dye sensitized solar cells (DSSCs). In this article we report a potential, Pt-free, carbon based nanocomposite as counter electrode catalyst for dye sensitized solar cells. Graphene oxide (GO) was made into reduced graphene oxide (SSrGO) by irradiating with light (Xe source). Suspension of SSrGO in DMF was spray coated onto fluorine doped tin oxide (FTO) coated glass substrate, followed by spray coat of single walled carbon nanohorns (SWCNH) suspension in DMF. SSrGO and SWCNH coated FTO glass substrate was investigated as an effective Pt-free composite counter electrode (CE) for DSSC and also showed the comparable catalytic activity with Pt. The test cell reveals power conversion efficiency (PCE) of 8.27%, whereas the DSSC module exhibited a PCE of 5.18%. By using the fabricated DSSC module, an electric motor (15 mW) was operated both in indoor and outdoor light conditions. The procedures followed in this work pave a way for the easy fabrication of composite CE towards transparent DSSC modules and further the integration of the DSSC module with the standard Si solar cell is of great potential for various real-time application.
引用
收藏
页码:568 / 575
页数:8
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