Polymer Stabilization of Lead(II) Perovskite Cubic Nanocrystals for Semitransparent Solar Cells

被引:197
作者
Guo, Yunlong [1 ]
Shoyama, Kazutaka [1 ]
Sato, Wataru [1 ]
Nakamura, Eiichi [1 ]
机构
[1] Univ Tokyo, Dept Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan
基金
日本科学技术振兴机构;
关键词
cubic nanocrystals; lead perovskite; polymers; semitransparent solar cells; stabilization; PERFORMANCE; EFFICIENT; STABILITY; DEPOSITION; TRIHALIDE;
D O I
10.1002/aenm.201502317
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lead (II) perovskite (PV, e.g., CH3NH3PbI3-xClx) with 3 wt% polyvinylpyrrolidone (PVP) produces an ≈90 nm film containing a PVP-PV composite consisting of ≈15-nm-sized PV nanocrystals. Solar cells using 3 wt% PVP-PV have several advantages over a device using nondoped PV, which include an increase in transparency, stability of the film, efficiency, and reproducibility. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页数:9
相关论文
共 36 条
[1]  
Asguez V. Y., 2005, J AM CHEM SOC, V127, P12504
[2]   EFFECT OF CRYSTAL SIZE-REDUCTION ON LATTICE SYMMETRY AND COOPERATIVE PROPERTIES [J].
AYYUB, P ;
PALKAR, VR ;
CHATTOPADHYAY, S ;
MULTANI, M .
PHYSICAL REVIEW B, 1995, 51 (09) :6135-6138
[3]   A Universal Interface Layer Based on an Amine-Functionalized Fullerene Derivative with Dual Functionality for Efficient Solution Processed Organic and Perovskite Solar Cells [J].
Azimi, Hamed ;
Ameri, Tayebeh ;
Zhang, Hong ;
Hou, Yi ;
Quiroz, Cesar Omar Ramirez ;
Min, Jie ;
Hu, Mengyao ;
Zhang, Zhi-Guo ;
Przybilla, Thomas ;
Matt, Gebhard J. ;
Spiecker, Erdmann ;
Li, Yongfang ;
Brabec, Christoph J. .
ADVANCED ENERGY MATERIALS, 2015, 5 (08)
[4]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[5]   High-performance semi-transparent polymer solar cells possessing tandem structures [J].
Chen, Chun-Chao ;
Dou, Letian ;
Gao, Jing ;
Chang, Wei-Hsuan ;
Li, Gang ;
Yang, Yang .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (09) :2714-2720
[6]   Semi-transparent polymer solar cells with 6% PCE, 25% average visible transmittance and a color rendering index close to 100 for power generating window applications [J].
Chen, Kung-Shih ;
Salinas, Jose-Francisco ;
Yip, Hin-Lap ;
Huo, Lijun ;
Hou, Jianhui ;
Jen, Alex K. -Y. .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (11) :9551-9557
[7]   Surfactant enhanced surface coverage of CH3NH3PbI3-xClx perovskite for highly efficient mesoscopic solar cells [J].
Ding, Yanli ;
Yao, Xin ;
Zhang, Xiaodan ;
Wei, Changchun ;
Zhao, Ying .
JOURNAL OF POWER SOURCES, 2014, 272 :351-355
[8]   Efficient, Semitransparent Neutral-Colored Solar Cells Based on Microstructured Formamidinium Lead Trihalide Perovskite [J].
Eperon, Giles E. ;
Bryant, Daniel ;
Troughton, Joel ;
Stranks, Samuel D. ;
Johnston, Michael B. ;
Watson, Trystan ;
Worsley, David A. ;
Snaith, Henry J. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (01) :129-138
[9]   Neutral Color Semitransparent Microstructured Perovskite Solar Cells [J].
Eperon, Giles E. ;
Burlakov, Victor M. ;
Goriely, Alain ;
Snaith, Henry J. .
ACS NANO, 2014, 8 (01) :591-598
[10]  
GASPERA ED, 2015, NANO ENERGY, V13, P249, DOI DOI 10.1016/J.NANOEN.2015.02.028