Spatially-confined crystallization of poly(vinylidene fluoride)

被引：0

作者：

Yang, XN ^{[1
]}

Kong, XH ^{[1
]}

Tan, SS ^{[1
]}

Li, G ^{[1
]}

Ling, W ^{[1
]}

Zhou, EL ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

来源：

POLYMER INTERNATIONAL | 2000年 / 49卷 / 11期

关键词：

poly(vinylidene fluoride); confined crystallization; polymer morphology; metastable; poly(methyl methacrylate);

D O I：

10.1002/1097-0126(200011)49:11<1525::AID-PI563>3.0.CO;2-I

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Nanometre-sized poly(vinylidene fluoride) (PVDF) particle domains in a confined space were obtained by blending PVDF with excess poly(methyl methacrylate) (PMMA). When these particles were small enough they showed beta -form structure, which was different from the structure of bigger particles or PVDF bulk. However, the beta -form was thermodynamically metastable because it could eventually be transformed to a more stable phase by annealing at a certain temperature. Larger particle domains were of identical phase to the bulk, indicating that small size favours the formation of the beta -form. (C) 2000 Society of Chemical Industry.

引用

页码：1525 / 1528

页数：4

共 19 条

[1]

BACHMANN M, 1979, J APPL PHYS, V50, P6095

[2] CHAIN CONFORMATIONS OF POLYVINYLIDENE FLUORIDE AS DERIVED FROM ITS VIBRATIONAL SPECTRUM [J].