Ordering and Phase Transitions in Ionic Liquid-Crystalline Films

被引：20

作者：

Sobota, Marek ^{[1
]}

Wang, Xinjiao ^{[3
]}

Fekete, Melinda ^{[4
]}

Happel, Markus ^{[1
]}

Meyer, Karsten ^{[2
,3
]}

Wasserscheid, Peter ^{[2
,4
]}

Laurin, Mathias ^{[1
]}

Libuda, Joerg ^{[1
,2
]}

机构：

[1] Univ Erlangen Nurnberg, Lehrstuhl Phys Chem 2, D-91058 Erlangen, Germany

[2] Univ Erlangen Nurnberg, Erlangen Catalysis Resource Ctr, D-91058 Erlangen, Germany

[3] Univ Erlangen Nurnberg, Lehrstuhl Anorgan Chem, D-91058 Erlangen, Germany

[4] Univ Erlangen Nurnberg, Lehrstuhl Chem Reakt Tech, D-91058 Erlangen, Germany

来源：

CHEMPHYSCHEM | 2010年 / 11卷 / 08期

关键词：

infrared reflection absorption spectroscopy; ionic liquids; phase transitions; structure elucidation; thin films; LANGMUIR-BLODGETT-FILMS; SELF-ASSEMBLED MONOLAYERS; INFRARED-SPECTROSCOPY; MOLECULAR-ORIENTATION; DISORDER TRANSITIONS; THERMAL-STABILITY; GAS SEPARATIONS; SILP CATALYSIS; FT-IR; BEHAVIOR;

D O I：

10.1002/cphc.201000144

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Watching phase transitions: Ordering processes and phase transitions in thin films of the liquid-crystalline ionic liquid 1,3-didodecylimidazolium tetrafluoroborate [C12C12IM][BF4] on Pt(111) (see picture) are studied by means of temperature-dependent IR reflection absorption spectroscopy. The method allows in situ monitoring of the structural properties of liquid-crystalline supported ionic liquid phase (SILP) catalysts under reaction conditions. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1632 / 1636

页数：5

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