Campanian Ignimbrite as raw material for lightweight aggregates

Aim of this research is an evaluation of the zeolitized facies of Campanian Ignimbrite as raw material for the production of lightweight expanded aggregates (LEA). A commercial product (Cab70) was used as reference for this rock. Tests were carried out on "pure" samples or mixed with an industrial waste mud (DPM-Dried Polishing Mud) deriving from a porcelain stoneware tile polishing process. This mud contains SiC, a phase known to act as bloating enhancer. Raw materials were subjected to mineralogical (XRPD-RIR method) and chemical (XRF) analyses. Bloating upon heating was measured (Leitz heating microscope) on Cab70, DPM and on three mixtures having the following Cab70/DPM ratios: 85/15 (Mix 1); 70/30 (Mix2); 50/50 (Mix3). LEA production was assessed both in static (muffle kiln) and in dynamic (rotating kiln) conditions by firing pellets, 3-8 mm in size, between 1220-1380 degrees C. The unit weight of the single particle was determined on fired and unfired products. All materials evidenced a decreasing density with temperature whereas the same parameter decreases with DPM increasing content. Cab70 LEAs never dropped below 0.90 g/cm(3), even at the highest temperature, whereas DPM LEAs range between 0.86 g/cm(3) (at 1260 degrees C) and 0.46 g/cm(3) (at 1380 degrees C). A direct but not linear relationship between DPM content and density was evidenced. Among the three mixtures, Mix2 showed the lowest DPM content able to produce the strongest densin, reduction. To get LEAs with the same density the rotating kiln required temperatures generally 60-80 degrees C higher than those of the muffle kiln. This difference should be related to the different thermal insulation of the two systems during firing. Two sets of LEAs were massively produced in dynamic conditions from Cab70 (at 1380 degrees C) and Mix2 (at 1300 degrees C). These latter showed better technical performances in terms of unit weight of the single particle (0.81 vs. 0.98 g/cm(3)), bulk unit weight (460 vs. 565 kg/m(3)), water absorption coefficients (1.4 vs. 5.5% after 24 h) and compressive strength of the particles (2.9 vs. 0.6 MPa). Differences in pore shape, dimension, abundance and spatial distribution were observed by SEM between the two sets. The technical features of these LEAs were comparable to some expanded clays, with similar grain size, commercialised in Italy. These results are worth interesting as they reveal new perspectives of application both for a rock characterized by a low exploitation cost and widely available in central-southern Italy, as well as for an industrial waste produced in high amount but not recycled at all. (C) 2006 Elsevier B.V. All rights reserved.