Dichloro(4′-phenyl-2,2′:6′,2"-terpyridine-κ3N)-zinc(II) monohydrate

被引：10

作者：

Tu, QD

Li, D

Wu, T

Yin, YG ^{[1
]}

Ng, SW

机构：

[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804021853

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Zn atom in each of the two symmetry-independent complex molecules of the title compound, [ZnCl2(C21H15-N-3)].H2O, shows trigonal-bipyramidal coordination as the N-heterocycle is able to span the two axial sites of the coordination polyhedron. One of the molecules occupies a position in the crystal structure such that it does not interact with any water molecule; the other interacts with two water molecules to give rise to a hydrogen-bonded chain that runs along the a axis of the triclinic unit cell.

引用

页码：M1403 / M1404

页数：2

共 6 条

[1]

*BRUK AXS INC, 2002, SADABS SAINT SMART

[2] THE COORDINATION CHEMISTRY OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE - THE SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURES OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE AND BIS(4'-PHENYL-2,2'-6',2''-TERPYRIDINE)NICKEL(II) CHLORIDE DECAHYDRATE [J].