Indium(I)-Catalyzed Asymmetric Allylation, Crotylation, and α-Chloroallylation of Hydrazones with Rare Constitutional and High Configurational Selectivities

被引：68

作者：

Chakrabarti, Ananya ^{[1
]}

Konishi, Hideyuki ^{[1
]}

Yamaguchi, Miyuki ^{[1
]}

Schneider, Uwe ^{[1
]}

Kobayashi, Shu ^{[1
]}

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, HFRE Div,ERATO,Japan Sci & Technol Agcy,Bunkyo Ku, Tokyo 1130033, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 10期

基金：

日本学术振兴会;

关键词：

asymmetric catalysis; boron; C-C coupling; indium; semicorrin; N-ACYLHYDRAZONES; ALLYLIC CARBONATES; PI-ALLYLPALLADIUM; INDIUM(I) IODIDE; ENANTIOSELECTIVE ALLYLATION; STRUCTURAL-CHARACTERIZATION; STEREOSELECTIVE-SYNTHESIS; PINACOLYL ALLYLBORONATE; MEDIATED ALLYLATION; MONOMERIC INDIUM(I);

D O I：

10.1002/anie.200906308

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydra-zone: The first example of asymmetric In catalysis had been developed. In I combined with a chiral semicorrin ligand (L*) is an effective catalyst for enantioselective allylation, crotylation and α-chloroallylation of hydrazones. In the two latter cases, C-C bond formations proceeded with high selectivity where both reactive aliphatic C-Cl and aromatic O-H bonds were tolerated. Chemical equation representation © 2010 Wiley-VCH Verlag GmbH & Co. KGaA www.angewandte.org.

引用

页码：1838 / 1841

页数：4

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[2]

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