Directional Crystallization by Floating Self-Assembly for Efficient and Stable Tin-based Perovskite Solar Cells

被引：29

作者：

Yang, Jia ^{[1
]}

Sheng, Wangping ^{[1
]}

Xiao, Shuqin ^{[1
]}

Liu, Gengling ^{[1
]}

Lin, Zhuojia ^{[1
]}

Tan, Licheng ^{[1
]}

Chen, Yiwang ^{[1
,2
]}

机构：

[1] Nanchang Univ, Coll Chem, Inst Polymers & Energy Chem IPEC, Nanchang 330031, Jiangxi, Peoples R China

[2] Jiangxi Normal Univ, Coll Chem, Inst Adv Sci Res iASR, Key Lab Funct Small Mol,Minist Educ, Nanchang 330022, Jiangxi, Peoples R China

来源：

CHEMISTRY OF MATERIALS | 2021年 / 33卷 / 12期

基金：

中国国家自然科学基金;

关键词：

HALIDE PEROVSKITES; THIN-FILMS; HETEROJUNCTION; PERFORMANCE; STABILITY; QUALITY; IODIDE; ACID;

D O I：

10.1021/acs.chemmater.0c04906

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tin-based perovskite materials have attracted intensive research due to its environmental friendliness and tremendous potential in the photovoltaic field. However, the extremely poor crystalline quality and awful stability of tin-based perovskite have restricted the further improvement in optoelectronic performance. Herein, a novel strategy of crystal orientate manipulation is proposed by introducing a self-assembly molecule, fluorinated-perylene diimide (F-PDI), which provides an external driving force to guide the orientated crystallization of perovskite in the vertical direction, and thus greatly promotes the effective transmission of carriers. The conductive F-PDI simultaneously serves as defect passivator and hydrophobic barrier layer, which boosts the photoelectric performance and contributes to the lattice robustness. As a result, the unencapsulated device based on F-PDI achieves considerable power conversion efficiency (PCE) of 9.49% and exhibits remarkable long-term stability, maintaining over 80% of its original efficiency after similar to 3000 h storage under light soaking.

引用

页码：4362 / 4372

页数：11

共 54 条

[41] Formation of cathode buffer layer by surface segregation of fluoroalkyl-modified ZnO for polymer solar cells [J].

Tan, Licheng ;

He, Zhijuan ;

Chen, Yiwang .

RSC ADVANCES, 2015, 5 (30) :23213-23223

[42] Relating the morphology of poly(p-phenylene vinylene)/methanofullerene blends to solar-cell performance [J].

van Duren, JKJ ;

Yang, XN ;

Loos, J ;

Bulle-Lieuwma, CWT ;

Sieval, AB ;

Hummelen, JC ;

Janssen, RAJ .

ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (05) :425-434

[43] 2D-Quasi-2D-3D Hierarchy Structure for Tin Perovskite Solar Cells with Enhanced Efficiency and Stability [J].

Wang, Fei ;

Jiang, Xianyuan ;

Chen, Hao ;

Shang, Yuequn ;

Liu, Hefei ;

Wei, Jingle ;

Zhou, Wenjia ;

He, Hailong ;

Liu, Weimin ;

Ning, Zhijun .

JOULE, 2018, 2 (12) :2732-2743

[44] Caffeine Improves the Performance and Thermal Stability of Perovskite Solar Cells [J].

Wang, Rui ;

Xue, Jingjing ;

Meng, Lei ;

Lee, Jin-Wook ;

Zhao, Zipeng ;

Sun, Pengyu ;

Cai, Le ;

Huang, Tianyi ;

Wang, Zhengxu ;

Wang, Zhao-Kui ;

Duan, Yu ;

Yang, Jonathan Lee ;

Tan, Shaun ;

Yuan, Yonghai ;

Huang, Yu ;

Yang, Yang .

JOULE, 2019, 3 (06) :1464-1477

[45] Electron-Transport-Layer-Assisted Crystallization of Perovskite Films for High-Efficiency Planar Heterojunction Solar Cells [J].

Wang, Ying-Chiao ;

Chang, Junwei ;

Zhu, Liping ;

Li, Xiaodong ;

Song, Changjian ;

Fang, Junfeng .

ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (09)

[46] Ion-Migration Inhibition by the Cation-π Interaction in Perovskite Materials for Efficient and Stable Perovskite Solar Cells [J].

Wei, Dong ;

Ma, Fusheng ;

Wang, Rui ;

Dou, Shangyi ;

Cui, Peng ;

Huang, Hao ;

Ji, Jun ;

Jia, Endong ;

Jia, Xiaojie ;

Sajid, Sajid ;

Eiseman, Ahmed Mourtada ;

Chu, Lihua ;

Li, Yingfeng ;

Jiang, Bing ;

Qiao, Juan ;

Yuan, Yongbo ;

Li, Meicheng .

ADVANCED MATERIALS, 2018, 30 (31)

[47] Self-organized buffer layers in organic solar cells [J].

Wei, Qingshuo ;

Nishizawa, Takeshi ;

Tajima, Keisuke ;

Hashimoto, Kazuhito .

ADVANCED MATERIALS, 2008, 20 (11) :2211-+

[48] SURFACE FREE ENERGY AND POLARITY OF ORGANIC PIGMENTS [J].

WU, S ;

BRZOZOWS.KJ .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1971, 37 (04) :686-&

[49] Efficient and stable tin-based perovskite solar cells by introducing π-conjugated Lewis base [J].

Wu, Tianhao ;

Liu, Xiao ;

He, Xin ;

Wang, Yanbo ;

Meng, Xiangyue ;

Noda, Takeshi ;

Yang, Xudong ;

Han, Liyuan .

SCIENCE CHINA-CHEMISTRY, 2020, 63 (01) :107-115

[50] High-Performance Perovskite Solar Cells with Excellent Humidity and Thermo-Stability via Fluorinated Perylenediimide [J].

Yang, Jia ;

Liu, Cong ;

Cai, Chunsheng ;

Hu, Xiaotian ;

Huang, Zengqi ;

Duan, Xiaopeng ;

Meng, Xiangchuan ;

Yuan, Zhongyi ;

Tan, Licheng ;

Chen, Yiwang .

ADVANCED ENERGY MATERIALS, 2019, 9 (18)

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