The synthesis, crystal, molecular and electronic structure of [ReCl2(NO)(py)3]

被引：3

作者：

Machura, B

Dziegielewski, JO

Bartczak, TJ

Kusz, J

机构：

[1] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland

[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland

[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 56卷 / 05期

关键词：

rhenium complexes; nitrosyl; X-ray structure; electronic structure; nitric oxide;

D O I：

10.1080/0095897031000092368

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In line with our investigations of rhenium nitrosyl complexes,, we have studied the reaction of [ReCl3(NO)(OPPh3)(PPh3)] with pyridine. The [ReCl2(NO)(PY)(3)] Complex obtained in this reaction has been characterised. by IR, electronic spectra and magnetochemical measurements; ligand field parameters and the electronic structure have been determined. The crystal and molecular structure of [ReCl2(NO)(PY)(3)] has been solved by the heavy atom method. Crystals of [ReCl2(NO)(PY)(3)] contain distorted octahedral molecules with the pyridine ligands in the mer-arrangement. The nitrosyl group is coordinated linearly to the rhenium atom as NO+.

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收藏

页码：417 / 425

页数：9

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