The synthesis, crystal, molecular and electronic structure of [ReCl2(NO)(py)3]

被引：3
|
作者：
Machura, B
Dziegielewski, JO
Bartczak, TJ
Kusz, J
机构：
[1] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland
[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland
[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 56卷 / 05期
关键词：
rhenium complexes; nitrosyl; X-ray structure; electronic structure; nitric oxide;
D O I：
10.1080/0095897031000092368
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In line with our investigations of rhenium nitrosyl complexes,, we have studied the reaction of [ReCl3(NO)(OPPh3)(PPh3)] with pyridine. The [ReCl2(NO)(PY)(3)] Complex obtained in this reaction has been characterised. by IR, electronic spectra and magnetochemical measurements; ligand field parameters and the electronic structure have been determined. The crystal and molecular structure of [ReCl2(NO)(PY)(3)] has been solved by the heavy atom method. Crystals of [ReCl2(NO)(PY)(3)] contain distorted octahedral molecules with the pyridine ligands in the mer-arrangement. The nitrosyl group is coordinated linearly to the rhenium atom as NO+.
引用
收藏
页码：417 / 425
页数：9
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