Hydrothermal synthesis of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5[V0.324+V0.685+O2PO4{P(OH)2}0.44]

被引：0
作者：
Ayyappan, P
Asnani, M
Ramanan, A [1 ]
Piffard, Y
机构：
[1] Indian Inst Technol, Dept Chem, New Delhi 110016, India
[2] Univ Nantes, CNRS, Chim Solide Lab, Inst Mat Nantes, Nantes, France
来源：
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES | 2003年 / 115卷 / 01期
关键词：
vanadyl phosphate; hydrothermal synthesis; intercalation; single crystal structure;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper we report the hydrothermal synthesis and characterisation of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)(0.5) [V0.324+V0.685+O2PO4(P(OH)(2)}(0.44)]. The phase purity of the solid was established using powder X-ray diffraction, single crystal X-ray diffraction, TGA, DTA, FTIR, UV-Vis and magnetic susceptibility measurements. Crystal data: orthorhombic, Prima, a=9.0289, b=8.8962 and c=15.9813 Angstrom, V=1283.7Angstrom(3), Z=8. The structure contains layers made of VO5 square pyramids and PO4 tetrahedra; adjacent layers are connected through disordered tetrahedral PO2(OH)(2) units. Ethylenediammonium cations occupy cavities in between the layers.
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页码：33 / 40
页数：8
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